Home
Class 12
CHEMISTRY
Consider the reaction of both reactants ...

Consider the reaction of both reactants the rate of the reaction increases by a factor of 8. However, if only the concentration of `"CI"_2` is doubled, the rate is increased by a factor of 2. The order of this reaction with respect to NO is:

A

3

B

0

C

1

D

2

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction with respect to NO, we can analyze the information provided in the question step by step. ### Step 1: Understand the Rate Law The rate of a reaction can be expressed by the rate law: \[ \text{Rate} = k[\text{Cl}_2]^x[\text{NO}]^y \] where \( k \) is the rate constant, \( x \) is the order of the reaction with respect to Cl2, and \( y \) is the order of the reaction with respect to NO. ### Step 2: Analyze the Given Information 1. When both reactants are present, the rate increases by a factor of 8. 2. When the concentration of Cl2 is doubled, the rate increases by a factor of 2. ### Step 3: Set Up the Equations From the second piece of information (doubling Cl2): - If we double the concentration of Cl2, the new rate becomes: \[ \text{Rate}_{\text{new}} = k[2\text{Cl}_2]^x[\text{NO}]^y \] This can be simplified to: \[ \text{Rate}_{\text{new}} = k(2^x[\text{Cl}_2]^x)[\text{NO}]^y = 2^x \cdot \text{Rate}_{\text{original}} \] Given that this increases the rate by a factor of 2: \[ 2^x = 2 \] This implies: \[ x = 1 \] ### Step 4: Use the First Condition Now, using the first condition (both reactants increasing the rate by a factor of 8): - The new rate when both reactants are considered is: \[ \text{Rate}_{\text{new}} = k[\text{Cl}_2]^x[\text{NO}]^y \] This can be expressed as: \[ \text{Rate}_{\text{new}} = k[\text{Cl}_2]^1[\text{NO}]^y = 8 \cdot \text{Rate}_{\text{original}} \] Substituting \( x = 1 \): \[ k[\text{Cl}_2]^1[\text{NO}]^y = 8 \cdot k[\text{Cl}_2]^1[\text{NO}]^y \] This simplifies to: \[ [\text{NO}]^y = 8 \] This implies: \[ y = 3 \] (since \( 2^3 = 8 \)) ### Step 5: Conclusion Thus, the order of the reaction with respect to NO is: \[ \text{Order with respect to NO} = y = 3 \] ### Final Answer The order of the reaction with respect to NO is **3**. ---

To determine the order of the reaction with respect to NO, we can analyze the information provided in the question step by step. ### Step 1: Understand the Rate Law The rate of a reaction can be expressed by the rate law: \[ \text{Rate} = k[\text{Cl}_2]^x[\text{NO}]^y \] where \( k \) is the rate constant, \( x \) is the order of the reaction with respect to Cl2, and \( y \) is the order of the reaction with respect to NO. ### Step 2: Analyze the Given Information ...
Promotional Banner

Topper's Solved these Questions

  • MOLECULARITY

    PHYSICS WALLAH|Exercise LEVEL-2|60 Videos
  • HYDROGEN

    PHYSICS WALLAH|Exercise LEVEL-2|58 Videos
  • ORGANIC CHEMISTRY

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |13 Videos

Similar Questions

Explore conceptually related problems

If the concentration of a reactant 'A' is doubled and the rate of its reaction increase by a factor of 2, the order of reaction with respect to 'A' is

For the reaction A rarr Products, it is found that the rate of reaction increases by a factor of 6.25 when concentration of A increases by a factor of 2.5 . Calculate the order of reaction with respect to A .

For a chemical reaction A rarr B , the rate of reaction increases by a factor of 1.837 when the concentration of A is increased by 1.5 time. The order of reaction with respect to A is:

For the reaction 2A+B rarr Products it is found that doubling the concentration of both reactants increases the rate by a factor of 8. But doubling the concentration of "B" alone only doubles the rate.What is the order of the reaction w.r.t to A?

The rate of reaction between two reactants A and B increases by a factor of 4 if the concentration of reactant B is doubled. The order of this reaction with respect to reactant B is

PHYSICS WALLAH-MOLECULARITY -NEET Past 5 Years Questions
  1. Mechanism of a hypothetical reaction X(2) + Y(2) rarr 2XY is given b...

    Text Solution

    |

  2. A first order reaction has a specific reaction rate of 10^(-2) s^(-1)....

    Text Solution

    |

  3. Consider the reaction of both reactants the rate of the reaction incre...

    Text Solution

    |

  4. For the reaction , XA + YB to ZC If (-d[A])/( dt) = (-d[B])/(dt) = (...

    Text Solution

    |

  5. The decomposition of phosphine [PH(3)] on tungsten at low pressure is ...

    Text Solution

    |

  6. The rate of a first-order reaction is 0.04 "mol L"^(-1) " s"^(-1) at 1...

    Text Solution

    |

  7. The addition of a catallystic during a chemical reaction alters which ...

    Text Solution

    |

  8. An increse in the concentration of the reactants of a reaction leads t...

    Text Solution

    |

  9. The rate constant for a first order reaction is 4.606 xx 10^(-3) s^(-1...

    Text Solution

    |

  10. In collision theory of chemical reaction, Z(AB) represents

    Text Solution

    |

  11. The half-life for a zero order reaction having 0.02 M initial concentr...

    Text Solution

    |

  12. If the rate constant for a first order reaction is k, the time (t) req...

    Text Solution

    |

  13. For the chemical reaction N(2)(g)+3H(2)(g)hArr2NH(3)(g) The correc...

    Text Solution

    |

  14. when initial concentration of the reactant is doubled, the half-life p...

    Text Solution

    |

  15. The correct difference between first and second order reactions is tha...

    Text Solution

    |

  16. Mechanism of a hypothetical reaction X(2) + Y(2) rarr 2XY is given b...

    Text Solution

    |

  17. A first order reaction has a specific reaction rate of 10^(-2) s^(-1)....

    Text Solution

    |

  18. Consider the reaction of both reactants 2NO + Cl2-->2NOCl,it has been ...

    Text Solution

    |

  19. For the reaction , XA + YB to ZC If (-d[A])/( dt) = (-d[B])/(dt) = (...

    Text Solution

    |

  20. The decomposition of phosphine [PH(3)] on tungsten at low pressure is ...

    Text Solution

    |