Home
Class 12
CHEMISTRY
Predict the correct intermediate and pro...

Predict the correct intermediate and product in the following reaction.
`H_(2)-C=CH overset(H_(2)O H_(2)SO_(2)) underset(H_(2)SO_(4)) to underset((A)) ("intermediante") to underset((B)) ("product")`

A

`A:H_(3) C- underset(SO_(4)) underset(|) (C)=CH_(2) B: H_(3)C- underset(O) underset(||)(C)-CH_(3)`

B

`A:H_(3) C- underset(OH) underset(|) (C)=CH_(2) B: H_(3)C- underset(O) underset(||)(C)-CH_(3)`

C

`A:H_(3) C- underset(OH) underset(|)(C)=CH_(2) B: H_(3)C- underset(SO_(4)) underset(||)(C)-CH_(2)`

D

`A:H_(3) C- underset(O) underset(|) (C)=CH_(2) B: H_(3)C-C-=H`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to predict the correct intermediate and product for the reaction involving H2C=CH2 (ethylene) with H2O and H2SO4. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Reactants The reactants in the reaction are ethylene (H2C=CH2) and water (H2O) in the presence of sulfuric acid (H2SO4). **Hint:** Look for the functional groups in the reactants that will participate in the reaction. ### Step 2: Understand the Reaction Mechanism In the presence of sulfuric acid, water can dissociate into H+ and OH-. The H+ ion will protonate the double bond of ethylene, leading to the formation of a carbocation intermediate. **Hint:** Remember that the addition of H+ to a double bond generates a carbocation. ### Step 3: Formation of the Carbocation Intermediate When H2C=CH2 is protonated, the double bond breaks, and a carbocation is formed. The more stable carbocation will be formed at the carbon that can accommodate the positive charge better. In this case, the intermediate can be represented as CH3-C^+(CH2)-OH, where the positive charge is on the more substituted carbon. **Hint:** Consider the stability of carbocations; more substituted carbocations are generally more stable. ### Step 4: Nucleophilic Attack by Water The hydroxide ion (OH-) from water will attack the positively charged carbon in the carbocation intermediate, resulting in the formation of an alcohol. **Hint:** Look for how nucleophiles interact with electrophiles in the reaction. ### Step 5: Identify the Final Product After the nucleophilic attack, the product will be an alcohol. In this case, the product formed will be CH3-CH(OH)-CH3, which is isopropanol (or propan-2-ol). **Hint:** Check the structure of the product to ensure it matches the expected outcome based on the reactants. ### Summary of the Intermediate and Product - **Intermediate (A):** The carbocation formed after the addition of H+ to the double bond. - **Product (B):** The final product after the nucleophilic attack by water, which is isopropanol (CH3-CH(OH)-CH3). ### Final Answer - Intermediate (A): CH3-C^+(CH2)-OH (carbocation) - Product (B): CH3-CH(OH)-CH3 (isopropanol)

To solve the problem, we need to predict the correct intermediate and product for the reaction involving H2C=CH2 (ethylene) with H2O and H2SO4. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Reactants The reactants in the reaction are ethylene (H2C=CH2) and water (H2O) in the presence of sulfuric acid (H2SO4). **Hint:** Look for the functional groups in the reactants that will participate in the reaction. ### Step 2: Understand the Reaction Mechanism ...
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBONS

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS|27 Videos
  • HALOALKANES AND HALOARENES

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |7 Videos
  • HYDROGEN

    PHYSICS WALLAH|Exercise LEVEL-2|58 Videos

Similar Questions

Explore conceptually related problems

Predict the correct intermediat and product in the following reaction reaction : H_(3)C-C-=CHoverset(H_(2)O,H_(2)SO_(4))underset(HgSO_(4))rarr underset((A))(Intermediate)rarrunderset((B))(pro duct)

H_(3)C-C-=CH overset(H_(2)O,H_(4)SO_(4))underset(HgSO_(4))to underset(A)("intermediate") to underset(B)("product")

Predict the correct intermediate and product in the following reaction. H_(3)C-C-CH underset(HgSO_(4))overset(H_(2)O,H_(2)SO_(4))to underset((A))("Intermediate")tounderset((B))("Product")

Predict the correct intermediate and product in the following reaction: H_(3)C-C-=Choverset(H_(2)O,H_(2)SO_(4))underset(HgSO_(4))to"Intermediate" to "Product"

Which is the product in the following reaction? H_(2)C=CH-underset(CH_(3))underset(|)(CH)-OHoverset(H_(2)CrO_(4))rarr

PHYSICS WALLAH-HYDROCARBONS-LEVEL-1
  1. Which of the following is the most stable Cation

    Text Solution

    |

  2. Predict the correct intermediate and product in the following reaction...

    Text Solution

    |

  3. Which compound cannot be formed from Wurtz

    Text Solution

    |

  4. Which of the following is called marsh gas?

    Text Solution

    |

  5. Which one is the correct order of acidity?

    Text Solution

    |

  6. The case of dehydrohalogenation for different halogensis in the order

    Text Solution

    |

  7. Which of the following is the predominant product in the reaction of H...

    Text Solution

    |

  8. The reaction represents : C(12)H(26) to C(6) H(12)+C(6)H(14)

    Text Solution

    |

  9. Ethylene can be separated from acetylene by passing the mixture throug...

    Text Solution

    |

  10. Ozonolysis products of 2-pentyne after decomposition of ozonide with w...

    Text Solution

    |

  11. Which of the following reacts with KMnO(4) but does not react with tol...

    Text Solution

    |

  12. The dihedral angle between the hydrogen atoms of two methyl groups in ...

    Text Solution

    |

  13. Which one is the most reactive towards electrophilic reagent?

    Text Solution

    |

  14. The following reaction is known as: C(6)H(6)+CH(3)Cl overset(AlCl(3)...

    Text Solution

    |

  15. In the following reaction, the major product is :

    Text Solution

    |

  16. Complete the following reaction

    Text Solution

    |

  17. The final major product of the following reaction is : CH(3)-CH(2)-C...

    Text Solution

    |

  18. Which of the following species is an intermediate in the reaction show...

    Text Solution

    |

  19. Maleic acid reacts with Br(2)//C Cl(4) The production

    Text Solution

    |

  20. Sodium salt of the following acid which is needed for the preparation ...

    Text Solution

    |