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The final major product of the following...

The final major product of the following reaction is :
`CH_(3)-CH_(2)-C-=C-H overset((1)NaNH_(2)) underset((2)CH_(3)CH_(2)Br) to`

A

`CH_(3)-CH-C-=C-CH_(2)-CH_(3)`

B

`CH_(3)-underset(CH_(2)CH_(3))underset(|)(CH)-C-=C-H`

C

`CH_(3)-CH_(2)- underset(NH_(2)) underset(|)(CH)-CH_(3)`

D

`H_(3)C-CH_(2)-C-=C-NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final major product of the given reaction, we will follow these steps: ### Step 1: Identify the Reactants The reactant provided is 1-butyne (CH₃-CH₂-C≡C-H) and the reagents are sodium amide (NaNH₂) and ethyl bromide (CH₃CH₂Br). ### Step 2: Role of Sodium Amide (NaNH₂) Sodium amide is a strong base. It will abstract the acidic hydrogen from the terminal alkyne (the hydrogen attached to the sp-hybridized carbon). This results in the formation of a terminal alkyne anion. **Reaction:** \[ \text{CH}_3\text{-CH}_2\text{-C}\equiv\text{C-H} + \text{NaNH}_2 \rightarrow \text{CH}_3\text{-CH}_2\text{-C}\equiv\text{C}^- + \text{NH}_3 \] ### Step 3: Formation of the Anion The anion formed is: \[ \text{CH}_3\text{-CH}_2\text{-C}\equiv\text{C}^- \] ### Step 4: Nucleophilic Attack The anion will act as a nucleophile and attack the electrophilic carbon in ethyl bromide (CH₃CH₂Br). The bromine atom is a good leaving group, which will leave as bromide ion (Br⁻). **Nucleophilic Attack:** \[ \text{CH}_3\text{-CH}_2\text{-C}\equiv\text{C}^- + \text{CH}_3\text{-CH}_2\text{Br} \rightarrow \text{CH}_3\text{-CH}_2\text{-C}\equiv\text{C-CH}_2\text{-CH}_3 + \text{Br}^- \] ### Step 5: Final Product The final major product of this reaction is: \[ \text{CH}_3\text{-CH}_2\text{-C}\equiv\text{C-CH}_2\text{-CH}_3 \] This compound is 1-pentyne. ### Conclusion Thus, the final major product of the reaction is 1-pentyne. ---

To determine the final major product of the given reaction, we will follow these steps: ### Step 1: Identify the Reactants The reactant provided is 1-butyne (CH₃-CH₂-C≡C-H) and the reagents are sodium amide (NaNH₂) and ethyl bromide (CH₃CH₂Br). ### Step 2: Role of Sodium Amide (NaNH₂) Sodium amide is a strong base. It will abstract the acidic hydrogen from the terminal alkyne (the hydrogen attached to the sp-hybridized carbon). This results in the formation of a terminal alkyne anion. ...
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