Home
Class 12
CHEMISTRY
Which one is the correct order of acidit...

Which one is the correct order of acidity?

A

`CH_(2)-CH_(3) gt CH_(3)=CH_(2) gt C-=CH gt CH=CH`

B

`CH_(2)=CH_(2) gt CH_(3)-CH= CH_(2) gt CH_(3)-C-=CH gt CH-=CH`

C

`CH=CH gt CH_(3)-C-=CH gt CH_(2) =CH_(2) gt CH_(3)-CH_(2)`

D

`CH-=CH gt CH_(2)= CH_(2) gt CH_(3)-C-= CH gt CH_(3)-CH)_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of acidity among hydrocarbons, we need to analyze the hybridization of the carbon atoms involved in the bonds. The acidity of a compound is influenced by the ability of the compound to donate protons (H+ ions), which is related to the hybridization of the carbon atoms and the percentage of s-character in the hybrid orbitals. ### Step-by-Step Solution: 1. **Understanding Acidity**: Acidity refers to the ability of a compound to donate protons (H+ ions). The more easily a compound can donate a proton, the stronger the acid it is. 2. **Hybridization and s-character**: The acidity of hydrocarbons is influenced by the hybridization of carbon atoms: - **sp hybridization**: 50% s-character - **sp² hybridization**: 33.33% s-character - **sp³ hybridization**: 25% s-character 3. **Comparing s-character**: The greater the s-character, the stronger the acid. This is because higher s-character means that the electrons are held closer to the nucleus, making it easier to release the H+ ion: - Triple bond (sp) > Double bond (sp²) > Single bond (sp³) 4. **Order of Acidity**: Based on the s-character: - **Triple bond (sp)** has the highest acidity. - **Double bond (sp²)** has moderate acidity. - **Single bond (sp³)** has the lowest acidity. 5. **Conclusion**: The correct order of acidity from highest to lowest is: - **Triple bond > Double bond > Single bond** ### Final Answer: The correct order of acidity is: **Triple bond > Double bond > Single bond**.

To determine the correct order of acidity among hydrocarbons, we need to analyze the hybridization of the carbon atoms involved in the bonds. The acidity of a compound is influenced by the ability of the compound to donate protons (H+ ions), which is related to the hybridization of the carbon atoms and the percentage of s-character in the hybrid orbitals. ### Step-by-Step Solution: 1. **Understanding Acidity**: Acidity refers to the ability of a compound to donate protons (H+ ions). The more easily a compound can donate a proton, the stronger the acid it is. 2. **Hybridization and s-character**: The acidity of hydrocarbons is influenced by the hybridization of carbon atoms: - **sp hybridization**: 50% s-character ...
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBONS

    PHYSICS WALLAH|Exercise LEVEL-1|40 Videos
  • HYDROCARBONS

    PHYSICS WALLAH|Exercise LEVEL-1|40 Videos
  • HALOALKANES AND HALOARENES

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |7 Videos
  • HYDROGEN

    PHYSICS WALLAH|Exercise LEVEL-2|58 Videos

Similar Questions

Explore conceptually related problems

Which is the correct order of acidity from weakest to strongest acid for these compounds :

Correct order of acidity is:

Write the correct order of acidity :

Which of the following is the correct order of acidity ?

Which among the following depicts the correct order of acidity ?

Select the correct order of acidity :

PHYSICS WALLAH-HYDROCARBONS-NEET PAST 5 YEARS QUESTIONS
  1. Hydrocarbon(A) reacts with bromine by substitution to form an alkyl br...

    Text Solution

    |

  2. The compound C(7)H(8) undergoes the following reactions : C(7)H(8) o...

    Text Solution

    |

  3. Which one is the correct order of acidity?

    Text Solution

    |

  4. The correct statement regarding the conformation is

    Text Solution

    |

  5. The compound that will react most readily with gaseous bromine has the...

    Text Solution

    |

  6. In pyrole, the electron density is maximum on

    Text Solution

    |

  7. In the given reaction, the product P is :

    Text Solution

    |

  8. The correct statement regarding the comparison of and eclipsed conform...

    Text Solution

    |

  9. For the following reaction : (A) CH(3)CH(2)CH(2)Br+KOH to CH(3)CH=CH...

    Text Solution

    |

  10. Which of the following is a free radical substitution reaction?

    Text Solution

    |

  11. Which of the following compounds is most reactive in electrophilic aro...

    Text Solution

    |

  12. The number of sigma (sigma) and pi(pi) bonds in pent-2-en-4-yne is:

    Text Solution

    |

  13. Among the following the reaction that produce through an electrophilic...

    Text Solution

    |

  14. Hydrocarbon (A) reacts with bromine by substitution to form an alkyl b...

    Text Solution

    |

  15. The compound C(7)H(8) undergoes the following reactions : C(7)H(8) o...

    Text Solution

    |

  16. Which one is the correct order of acidity ?

    Text Solution

    |

  17. The correct statement regarding the conformation is

    Text Solution

    |

  18. The compound that will react most readily with gaseous bromine has the...

    Text Solution

    |

  19. Which of the following can beused as the halide component for friedel-...

    Text Solution

    |

  20. In pyrole, the electron density is maximum on

    Text Solution

    |