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Lucas reagent is:...

Lucas reagent is:

A

Conc. HCl and anhydrous `ZnCl_(2)`

B

Conc. `HNO_(3)` and anhydrous `ZnCl_(2)`

C

Dil. HCl and anhydrous `ZnCl_(2)`

D

Dil. `HNO_(3)` and anhydrous `ZnCl_(2)`

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The correct Answer is:
**Step-by-Step Solution:** 1. **Definition of Lucas Reagent**: Lucas reagent is a solution used in organic chemistry to differentiate between primary, secondary, and tertiary alcohols. It is composed of anhydrous zinc chloride (ZnCl2) dissolved in concentrated hydrochloric acid (HCl). 2. **Purpose of Lucas Test**: The primary purpose of the Lucas test is to determine the type of alcohol present in a sample. The test exploits the reactivity of alcohols with Lucas reagent, leading to the formation of alkyl chlorides. 3. **Reaction Mechanism**: - **Primary Alcohols**: When a primary alcohol reacts with Lucas reagent, it forms an alkyl chloride, but the turbidity (cloudiness) appears only after heating. This is because primary alcohols are less reactive and require more time to form the product. - **Secondary Alcohols**: In the case of secondary alcohols, the reaction also produces alkyl chlorides, but turbidity is observed within about 5 minutes, indicating a moderate reactivity. - **Tertiary Alcohols**: Tertiary alcohols react very quickly with Lucas reagent, leading to immediate turbidity due to the rapid formation of alkyl chlorides. 4. **Conclusion**: The Lucas test is a valuable qualitative test in organic chemistry for distinguishing between different types of alcohols based on the speed of turbidity formation after the addition of Lucas reagent. 5. **Correct Answer**: The Lucas reagent is anhydrous ZnCl2 in concentrated HCl. ---

**Step-by-Step Solution:** 1. **Definition of Lucas Reagent**: Lucas reagent is a solution used in organic chemistry to differentiate between primary, secondary, and tertiary alcohols. It is composed of anhydrous zinc chloride (ZnCl2) dissolved in concentrated hydrochloric acid (HCl). 2. **Purpose of Lucas Test**: The primary purpose of the Lucas test is to determine the type of alcohol present in a sample. The test exploits the reactivity of alcohols with Lucas reagent, leading to the formation of alkyl chlorides. 3. **Reaction Mechanism**: - **Primary Alcohols**: When a primary alcohol reacts with Lucas reagent, it forms an alkyl chloride, but the turbidity (cloudiness) appears only after heating. This is because primary alcohols are less reactive and require more time to form the product. ...
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PHYSICS WALLAH-ALCOHOLS, PHENOLS AND ETHERS -NEET PAST 5 YEARS QUESTIONS
  1. Lucas reagent is:

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  2. Reaction between acetone and methyl magnesium chloride followed by hyd...

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  3. Anisole on cleavage with HI gives:

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  4. Which of the following substituted phenols is the strongest acid?

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  5. CH(3)CH(2)CH=CH(2)underset(H(2)O.H(2)O(2).)overset(B(2)H()rarrZ What...

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  6. The compound that is most difficult to protonate is

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  7. The structure of intermediate A in the following reaction, is

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  8. Identify the major products P, Q and R in the following sequence of re...

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  9. The compound A on treatment with Na gives B, and with PCl(5) gives C. ...

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  10. In the reaction the electrophile involved is:

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  11. The heating of phenyl-methyl ethers with HI produces .

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  12. Which one is the most acidic compound?

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  13. The oxidation of phenol with chromic acid gives

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  14. Identify A and predict the type of reaction:

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  15. The reaction: can be classified as?

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  16. Reaction between acetone and methyl magnesium chloride followed by hyd...

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  17. Anisole on cleavage with HI gives:

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  18. Which of the following substituted phenols is the strongest acid?

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  19. CH(3)CH(2)CH=CH(2)underset(H(2)O.H(2)O(2).OH^-)overset(B(2)H(6))rarrZ ...

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  20. The compound that is most difficult to protonate is

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  21. The structure of intermediate A in the following reaction, is

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