Home
Class 12
CHEMISTRY
Chlorobenzene overset("reaction X")rarr"...

Chlorobenzene `overset("reaction X")rarr"Phenol"overset("reaction Y")rarr` salicylaldehyde
X and Y reactions are respectively:

A

Fries rearrangement and kolbe - schmidt

B

Cumene and Reimer - Tiemann

C

Dow and Reimer - Tiemann

D

Dow and Friedal craft

Text Solution

AI Generated Solution

The correct Answer is:
To convert chlorobenzene to phenol and then to salicylaldehyde, we need to identify the reactions involved, which are referred to as reaction X and reaction Y. ### Step-by-Step Solution: 1. **Identify Reaction X:** - Chlorobenzene (C6H5Cl) can be converted to phenol (C6H5OH) through a reaction known as the **Dawes process**. This involves treating chlorobenzene with sodium hydroxide (NaOH) under specific conditions (high temperature and pressure). - **Reaction:** \[ \text{C}_6\text{H}_5\text{Cl} + \text{NaOH} \xrightarrow{\text{623 K, 300 atm}} \text{C}_6\text{H}_5\text{OH} + \text{NaCl} \] 2. **Identify Reaction Y:** - Phenol can be converted to salicylaldehyde (C7H6O) through a reaction known as the **Riemann-Tiemann reaction**. This involves the reaction of phenol with chloroform (CHCl3) in the presence of a strong base (NaOH), which generates dichlorocarbene (CCl2) that acts as a nucleophile and replaces a hydrogen atom on the phenol. - **Reaction:** \[ \text{C}_6\text{H}_5\text{OH} + \text{CHCl}_3 + \text{NaOH} \rightarrow \text{C}_6\text{H}_4(\text{OH})(\text{CHO}) + \text{NaCl} + \text{H}_2\text{O} \] ### Summary of Reactions: - **Reaction X:** Dawes process (Chlorobenzene to Phenol) - **Reaction Y:** Riemann-Tiemann reaction (Phenol to Salicylaldehyde) ### Final Answer: - Reaction X is the **Dawes process**. - Reaction Y is the **Riemann-Tiemann reaction**.

To convert chlorobenzene to phenol and then to salicylaldehyde, we need to identify the reactions involved, which are referred to as reaction X and reaction Y. ### Step-by-Step Solution: 1. **Identify Reaction X:** - Chlorobenzene (C6H5Cl) can be converted to phenol (C6H5OH) through a reaction known as the **Dawes process**. This involves treating chlorobenzene with sodium hydroxide (NaOH) under specific conditions (high temperature and pressure). - **Reaction:** \[ ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS AND ETHERS

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |28 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |28 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |16 Videos

Similar Questions

Explore conceptually related problems

i. SiCl_4 overset (H_2O) (rarr) (X) overset (100^@C) (rarr)(Y) In the above reaction (X) and (Y) respectively are :

Silver cyanide overset(Delta)rarr"Silver"+Aoverset(OH^-)rarrX+Y+H_2O In the above sequence of reaction A,X,Y are respectively.

Knowledge Check

  • Chlorobenzene overset("Reaction")underset(X)rarr "Phenol" overset("Reaction")underset(Y) rarr Salicylaldehyde X and Y reaction respectively are

    A
    Fries rearrangement and Kolbe-Schmidt
    B
    Cumene and Reimer-Tiemann
    C
    Dow and Reimer-Tiemann
    D
    Dow and Friedel-Craft
  • Chlorobenzene overset("Reaction-(X)")to Phenol overset("Reaction-(Y)")to Salicylaldehyde. The reaction (s) 'X ' and 'Y respectively are

    A
    Fries rearrangement and Kolbe
    B
    Cumene and Reimer-Tiemann
    C
    Dow and Reimer-Tiemann
    D
    Dow and Sandmeyer.
  • X overset(Y)rarr Benxoquinone. Identify X and Y in this reaction

    A
    X is cyclohexanol, Y is Zn
    B
    X is phenol, Y is `Na_2Cr_2O_7//H_2SO_4`
    C
    X is Cylohex-2-ene-1-ol, Y is `Na_2Cr_2O_7//H_2SO_4`
    D
    X is phenol, Y is Zn
  • Similar Questions

    Explore conceptually related problems

    C_(2)H_(5)OH+SOCl_(2) overset("Pyridine")rarr x + y + z , in the reaction x, y and z respectively are

    N_2+H_2rarr[X](g)overset(CO_2,"Pressure")rarr[Y]overset("Heat")rarr[Z]+H_2O In the above sequence of reaction, [Y] and [Z] are respectively.

    The following reaction is known as : Phenol overset(1.CHCl_(3)//NaOH) to Salicylaldehyde

    In the given reaction C_6H_5-CH_2-CH_3overset(NBS)rarr(X)overset(Alc.KOH//Delta)rarr(Y) In the given reaction X and Y respectively are

    Identify x, y, z for the following metallurgical process.Metal sulphide overset(x)rarr Metal oxide overset(y)rarr Impure metal overset(z)rarr pure metal. x, y and z are respectively