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The bond angle in H(2) S is:...

The bond angle in `H_(2) S` is:

A

`gt NH_3`

B

Same as in `BeCl_2`

C

`gt H_(2)Se, ltH_2O`

D

Same as in `CH_4`

Text Solution

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The correct Answer is:
C

Bond angle of hydrides of group 16 elements are
`H_2O gtH_2S gt H_(2)Se gt H_2 Te`
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The bond angle in H_2S is

Chemical bonding between two atoms is necessarily associated with an electrical moment arising out of the difference in electroegativity of two atoms. This means that every bond carries with it an electrical moment called the ''bond moment''. The dipole moment of a molecule is really the vectorial sum of the individual bond moment present in it. To compute the dipole moment it is necessary to find out the values of various bond moment. In the following table, dipole moment of different bonds are as given. {:(,rarr,rarr,rarr),("Bond",H-C,C-Cl,C=0),("Bond moments",0.4 D,1.5 D,2.5 D):} The group moments of few groups as given {:("Group",NO_(2),OH,CN,CH_(3)),("Direction of dipole","Towards N","Towards O","Towards N","Away from "CH_(3)),("Dipole moment",4D,1.6D,3.8D,0.4D):} The bond angle in H_(2)S is 97^(@) and its dipole moment is 1.5 D. The S-H bond distance is 0.15 nm. Therefore, approximate percentrage ionic cjaracter pf S-H bond is (neglect the effect of dipole moment of lone pair on sulphur atom in H_(2)S ). (Given : [cos 97^(@)=-0.121 and sqrt(0.88)=0.94] )

Bond angle in H_(2)O is

The bond angle of H_(2)Se is best described as

What is the H-S-H bond angle in H_(2)S ?

The bond angle in H_2O is nearly 105^@ whereas bond angle in H_2 S is nearly 92^@ . This is because.

Why H-S-H bond angle in H_(2)S is smaller than H-O-H bond angle in H_(2)O ?

PHYSICS WALLAH-CHEMICAL BONDING AND MOLECULAR STRUCTURE -NEET Past 5 Years Questions
  1. The bond angle in H(2) S is:

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  2. Which of the following set of molecules will have zero diplole moment?

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  3. Identify a molecule which does not exist.

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  4. How many sp^2 hybridised carbon atoms and pi bonds respectively are pr...

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  5. The potential energy(y) curve for H2 formation as a function of inrtnu...

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  6. Identify the wrongly matched pair.

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  7. Which of the following diatomic molecular species has only pi bonds ac...

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  8. Identify the incorrect statement related to PCI5 from the following:

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  9. Consider the following species CN^(-),CN^(-),NO and CN. Which one ...

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  10. Which of the following pairs of species have the same bond order ?

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  11. The species, having bond angles of 120^@ is

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  12. which one of the following ions is not tetrahedral in shape ?

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  13. Which of the following hydrides has the largent bond angle ?

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  14. Which one of the following compounds shows the presence of intramolecu...

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  15. In which of the following moleucles, all atoms are coplanar?

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  16. Among the following which one is a wrong statement?

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  17. The hybridisations of atomic orbitals of nitrogen in NO2, NO3^(-) and ...

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  18. Which of the following pairs of ions is isoelectronic and isostructur...

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  19. Consider the molecules CH(4), NH3 and H2O What of the given statement ...

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  20. Predict the correct order omong the following:

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  21. Which of the following set of molecules will have zero dipole moment?

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