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Which of the following has been an order...

Which of the following has been an order of % p-character ?

A

`sp lt sp^2 lt sp^3`

B

`sp^3 lt sp^2 lt sp`

C

`sp^2 lt sp^3 lt sp`

D

`sp^2 lt sp lt sp^3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of % p-character in different hybridizations (sp, sp², and sp³), we need to analyze the hybridization types and their respective p-character percentages. Here’s a step-by-step breakdown: ### Step 1: Understand Hybridization Types - **sp Hybridization**: This involves the mixing of one s orbital and one p orbital. Thus, the hybridization results in two sp hybrid orbitals. - **sp² Hybridization**: This involves the mixing of one s orbital and two p orbitals, resulting in three sp² hybrid orbitals. - **sp³ Hybridization**: This involves the mixing of one s orbital and three p orbitals, resulting in four sp³ hybrid orbitals. ### Step 2: Calculate % p-character for Each Hybridization 1. **For sp Hybridization**: - % s-character = 50% (1 s orbital out of 2 total orbitals) - % p-character = 50% (1 p orbital out of 2 total orbitals) 2. **For sp² Hybridization**: - % s-character = 33.33% (1 s orbital out of 3 total orbitals) - % p-character = 66.66% (2 p orbitals out of 3 total orbitals) 3. **For sp³ Hybridization**: - % s-character = 25% (1 s orbital out of 4 total orbitals) - % p-character = 75% (3 p orbitals out of 4 total orbitals) ### Step 3: Order the % p-character Now we can summarize the % p-character for each hybridization: - sp: 50% p-character - sp²: 66.66% p-character - sp³: 75% p-character ### Step 4: Arrange in Order From the calculations: - sp³ has the highest % p-character (75%) - sp² follows with (66.66%) - sp has the lowest % p-character (50%) Thus, the order of % p-character is: **sp³ > sp² > sp** ### Final Answer The order of % p-character is: **sp³ > sp² > sp** ---

To determine the order of % p-character in different hybridizations (sp, sp², and sp³), we need to analyze the hybridization types and their respective p-character percentages. Here’s a step-by-step breakdown: ### Step 1: Understand Hybridization Types - **sp Hybridization**: This involves the mixing of one s orbital and one p orbital. Thus, the hybridization results in two sp hybrid orbitals. - **sp² Hybridization**: This involves the mixing of one s orbital and two p orbitals, resulting in three sp² hybrid orbitals. - **sp³ Hybridization**: This involves the mixing of one s orbital and three p orbitals, resulting in four sp³ hybrid orbitals. ### Step 2: Calculate % p-character for Each Hybridization ...
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