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Identify the reaction from following hav...

Identify the reaction from following having top position is EMF series (Std. Red. Potential) according to their electrode potential at 298 K

A

`Fe^(2+) + 2e^(-) to Fe(s)`

B

`Au^(3+) + 3e^(-) to Au(s)`

C

`K^(+) + "1e"^(-) to K(s)`

D

`Mg^(2+) + 2e^(-) to Mg(s)`

Text Solution

Verified by Experts

The correct Answer is:
B

`Au^(3+) + 3e^(-) to Au(s), E^(@) = 1.40 V`
`Fe^(2+) + 2e^(-) to Fe(s), E^(@) =-0.44 V`
`Mg^(2+) + 2e^(-) to Mg(s) E^(@) to -2.36 V`
`K^(+) + 1e^(-) to K(s) E^(@) =-2.93 V`
`Au^(3+)` occupies the top position in the electrochemical series.
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