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The final major product of the following...

The final major product of the following reaction is :
`CH_(3)-CH_(2)-C-=C-H overset((1)NaNH_(2)) underset((2)CH_(3)CH_(2)Br) to`

A

`CH_(3)-CH_(2)-C-=C-CH_(2)-CH_(3)`

B

`CH_(3)-underset(CH_(2)CH_(3))underset(|)(CH)-C-=C-H`

C

`CH_(3)-CH_(2)- underset(NH_(2)) underset(|)(CH)-CH_(3)`

D

`H_(3)C-CH_(2)-C-=C-NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final major product of the given reaction, we will follow these steps: ### Step 1: Identify the Reactant The reactant is butyne, specifically 1-butyne, which can be represented as: \[ \text{CH}_3\text{CH}_2\text{C} \equiv \text{CH} \] ### Step 2: Reaction with Sodium Amide (NaNH₂) Sodium amide (NaNH₂) is a strong base. When it reacts with 1-butyne, it abstracts the acidic hydrogen from the terminal alkyne (the hydrogen attached to the carbon of the triple bond). This results in the formation of a carbon anion: \[ \text{CH}_3\text{CH}_2\text{C} \equiv \text{C}^- \] Here, the negative charge is stabilized by the sodium ion (Na⁺). ### Step 3: Nucleophilic Attack on Ethyl Bromide (CH₃CH₂Br) Next, we introduce ethyl bromide (CH₃CH₂Br) to the reaction. The carbon anion formed in the previous step acts as a nucleophile and attacks the carbon atom in ethyl bromide that is bonded to the bromine atom. This leads to the displacement of bromide ion (Br⁻) and the formation of a new carbon-carbon bond: \[ \text{CH}_3\text{CH}_2\text{C} \equiv \text{C}^- + \text{CH}_3\text{CH}_2\text{Br} \rightarrow \text{CH}_3\text{CH}_2\text{C} \equiv \text{C-CH}_2\text{CH}_3 + \text{NaBr} \] ### Step 4: Final Product Formation The product formed from this reaction is an internal alkyne with six carbon atoms: \[ \text{CH}_3\text{CH}_2\text{C} \equiv \text{C-CH}_2\text{CH}_3 \] This compound is known as hex-3-yne. ### Conclusion The final major product of the reaction is: \[ \text{Hex-3-yne} \]

To determine the final major product of the given reaction, we will follow these steps: ### Step 1: Identify the Reactant The reactant is butyne, specifically 1-butyne, which can be represented as: \[ \text{CH}_3\text{CH}_2\text{C} \equiv \text{CH} \] ### Step 2: Reaction with Sodium Amide (NaNH₂) Sodium amide (NaNH₂) is a strong base. When it reacts with 1-butyne, it abstracts the acidic hydrogen from the terminal alkyne (the hydrogen attached to the carbon of the triple bond). This results in the formation of a carbon anion: ...
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