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What type of isomerism is shown by the ...

What type of isomerism is shown by the following coordination compounds ?
`[Pt Cl_(2)(NH_(3))_(4)]Br_(2) and [Pt Br_(2)(NH_(3))_(4)]Cl_(2)`.
Write their IUPAC names.

Text Solution

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`[Pt Cl_(2)(NH_(3))_(4)]Br_(2) and [Pt Br_(2)(NH_(3))_(4)]Cl_(2)`
shows ionisation isomerism.
`[Pt Cl_(2)(NH_(3))_(4)]Br_(2)-`
Dichloridotetraammineplatinum(II)bromide/ Tetraamminedichloridoplatinum (IV)bromide
and `[PtBr_(2)(NH_(3))_(4)]Cl_(2)-`
Dibromidotetraammineplatinum(II)chloride/ Tetraamminedibromidoplatinum(IV) chloride
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