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An element occurs in bcc structure. It h...

An element occurs in bcc structure. It has a cell edge length of 250 pm. Calculate the molar mass if its density is 8.0 g `cm^(-3)` . Also calculate the radius of an atom of this element.

Text Solution

Verified by Experts

Given, cell edge length, `a = 250 p m = 250xx10^(-10)cm`
Density = `8g cm^(-3)`
For boc cell, number of atoms, Z = 2
Molar mass, M=?
We know that, density, `d= (Z*M)/(a^(3)*N_(A))`
or `8 g cm^(-3)= (2xxM)/((250xx10^(-10) cm)^(3) (6.022 xx 10^(23)"mol"^(-1)))`
or `M=((250xx10^(-10)cm)^(3)(6.022 xx 10^(23)"mol"^(-1)))/(2)xx 8 g cm^(-3)`
`=(9.409xx 8)/(2)`
`=37.64"g mol"^(-1)`
For bcc unit cell, `4r=sqrt(3)a`
Radius, `r=(sqrt(3)*a)/(4)=(1.732xx250)/(4)`
`=108.25` pm
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