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Among the isomeric alkanes of molecular ...

Among the isomeric alkanes of molecular formula `C_(5)H_(12)`, identify the one that on photochemical chlorination yields
a single monochloride

Text Solution

Verified by Experts

A single monochloride (IV) can be produced only when all the hydrogen atoms are equivalent. This isomer must be symmetrical. Its structure is given by (I).
`underset("(I)")(H_(3)C-undersetunderset(CH_(3))(|)oversetoverset(CH_(3))(|)(C)-CH_(3))+Cl_(2)overset(hv)rarrunderset("1-chloro-2, 2-dimethylpropane")(H_(3)C-undersetundersetunderset(("IV"))(CH_(3))(|)oversetoverset(CH_(3))(|)(C)-CH_(2)Cl+HCl)`
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Knowledge Check

  • The number of aldehydes of molecular formula C_5H_10O is :

    A
    2
    B
    3
    C
    4
    D
    5
  • The number of isomeric alcohols of formula C_(4)H_(10)O is:

    A
    2
    B
    4
    C
    7
    D
    8
  • The number of isomeric alcohols of formula C_4H_(10)O is:

    A
    2
    B
    4
    C
    7
    D
    8
  • Similar Questions

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    The number of aldehydes of molecular formula C_5H_10O is :

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    The number of isomeric alcohols of formula C_4H_(10)O is:

    The compound having the molecular formula C_3H_9N represents:

    The compound having molecular formula C_4H_10O can show: