Arrange each set of compounds in the order of increasing boiling points.
Bromomethane, bromoform, chloromethane, dibromomethane

Explanation

For the same alkyl group, boiling point increases with the size of the halogen atom. Thus, boiling point of bromomethane is higher than that of chloromethane. Further, the boiling point increases as the number of halogen atoms increases.
Thus, the boiling point of bromoform with three Br atoms is highest followed by dibromomethane with two Br atoms while that of bromomethane containing only one Br atom is lowest. Therefore, the arrangement of the given compounds in the order of increasing boiling points is as follows :
`CH_(3)Cl` (chloromethane) `ltCH_(3)Br` (bromomethane) `ltCH_(2)Br_(2)` (dibromomethane) `ltCHBr_(3)` (bromoform).