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A compound 'A' having molecular formula `C_(2)H_(5)O_(2)N`, on reaction with Sn and conc. HCl gives a compound B which when treated with `NaNO_(2)` and dil. HCl gave compound C having molecular formula `C_(2)H_(6)O`. The compound C when treated with Na metal give effervescenes and when reacts with `CrO_(3)` give a saturated aldehyde having 2 carbon atoms. Determine the structures and names of A, B and C along with the sequence of reactions.

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According the question, the reaction takes place as follows:
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C_2H_5O_2N on reaction with Sn and conc. HCL gives a compound 'B' which when treated with NaNO_2 and HCL gave the compound 'C' having M.F C_2H_6O .Then compound 'C ' when treated with 'Na' metal gives effervescence and when react with CrO_3 gives a saturated aldehyde.Determine structures and name of A, B,C.

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A compound A of molecular formula C_(3)H_(7)O_(2)N on reaction with iron and concentrated HCl gives a compound B of molecular formula C_(3)H_(9)N . Compound B on treatment with NaNO_(2) and HCl gives another compound C of molecular formula C_(3)H_(8)O . Compound C gives effervescence with sodium. On oxidation with CrO_(3) , compound C gives a saturated aldehyde containing three carbon atoms. Deduce the structures of compounds A, B and C and write the equations of the reactions involved.

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A compound (A) having molecular formula C_3 H_7 NO_2 reacts with Sn and Conc.HCl to give compound (B). Compound (B) reacts with solid NaNO_2 and dil HCl at 273K to give compound C, which on treatment with SOCl_2 gives compound (D). Write the structure of the compound A, B, C & D.

ARIHANT PUBLICATION-AMINES-PART II (Questions For Practice (Long Answer Type Questions))
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  2. Write the structure of main products when aniline reacts with the foll...

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  3. Write the structure of main products when aniline reacts with the foll...

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  4. Arrange the following in the increasing order of their boiling point ...

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  5. Give a simple chemical test to distinguish between the following pair ...

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  6. An aromatic compound 'A' of molecular formula C(7)H(6)O(2) undergoes a...

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  7. Give any two methods for the preparation of primary amine. How does it...

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  8. Give any two methods for the preparation of primary amine. How does it...

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  9. How can you show that amines are basic ?

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  10. How is methyl amine prepared from nitromethane and acetamide? How does...

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  11. Write the structure formulae of all the isomeric amines with molecular...

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  12. How is methylamine prepared from nitromethane and acetamide? How does ...

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  13. What are different types of aliphatic amines? Describe two general met...

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  14. What are different types of aliphatic amines? Describe two general met...

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  15. How is ethylamine prepared from C(2)H(5)NO(2) and CH(3)CH(2)CONH(2) ? ...

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  16. Which is more basic NH(3) or CH(3)NH(2)?

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  17. A compound A of molecular formula C(3)H(7)O(2)N on reaction with iron ...

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  18. An organic compound A having molecular formula C(2)H(5)O(2)N on treatm...

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  19. A compound 'A' having molecular formula C(2)H(5)O(2)N, on reaction wit...

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