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The correct order of the stoichiometries...

The correct order of the stoichiometries of `AgCl` formed when `AgNO_3` in excess is treated with the complexes: `CoCl_(3).6NH_3, CoCl_(3).5NH_3, CoCl_(3). 4NH_3` respectively is:

A

`2AgCl,3AgCl,1AgCl`

B

`1AgCl,3AgCl,2AgCl`

C

`3AgCl,1AgCl,2AgCl`

D

`3AgCl,2AgCl,1AgCl`

Text Solution

Verified by Experts

The correct Answer is:
D
Complexes are respectively `[Co(NH_(3))_(6)]Cl_(3+)[Co(NH_(3))_(5)Cl]Cl_(2) and [Co(NH_(3))_(4)Cl_(2)]Cl`.
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The correct order of stoichiometries of AgCI formed when AgNO_(3) in excess is treated with the complex: CoCI_(3) . 6NH_(3), CoCI_(3) . 5 NH_(3), CoCI_(3) . 4NH_(3) respectively is:

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