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What is the name of the following reacti...

What is the name of the following reaction?
`CH_3-CH_2-CH_2Br underset("Dry acetone")overset(NaI)(rarr) CH_3CH_2CH_2I`

A

Sandmeyer reaction

B

Gattermann reaction

C

Finkelstein reaction

D

Swarts reaction

Text Solution

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The correct Answer is:
To determine the name of the reaction given by the equation: \[ \text{CH}_3-\text{CH}_2-\text{CH}_2\text{Br} \xrightarrow{\text{Dry acetone}} \text{NaI} \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{I} \] we can analyze the components and the process involved. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is propyl bromide (CH₃-CH₂-CH₂Br). - The reagent used is sodium iodide (NaI) in dry acetone. 2. **Understanding the Reaction**: - Sodium iodide (NaI) is a source of iodide ions (I⁻). - In dry acetone, sodium iodide facilitates the substitution of bromine (Br) with iodine (I). 3. **Type of Reaction**: - This reaction involves the substitution of one halogen (Br) with another halogen (I). - The mechanism involved here is typically an \( S_N2 \) reaction, where the nucleophile (I⁻) attacks the carbon atom bonded to the leaving group (Br), resulting in the formation of propyl iodide (CH₃-CH₂-CH₂I). 4. **Name of the Reaction**: - This specific reaction is known as the **Finkelstein reaction**. It is characterized by the exchange of halogens, particularly when sodium iodide is used to convert alkyl bromides or chlorides to alkyl iodides in the presence of a polar aprotic solvent like acetone. ### Final Answer: The name of the reaction is the **Finkelstein reaction**. ---
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