Home
Class 12
CHEMISTRY
Which of the following compound does not...

Which of the following compound does not give iodoform test ?

A

Penta-3-one

B

Penta-2-one

C

Propanone

D

Ethanol

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following compounds does not give the iodoform test, we need to understand the conditions under which the iodoform test is positive. The iodoform test is typically given by: 1. **Methyl ketones** (compounds with the structure RCOCH3, where R can be any alkyl group). 2. **Ethanol** and other primary alcohols that can be oxidized to methyl ketones. 3. **Secondary alcohols** that can be oxidized to methyl ketones. The key factor for a compound to give a positive iodoform test is the presence of an **alpha methyl group** (a methyl group adjacent to the carbonyl carbon). ### Step-by-Step Solution: 1. **Identify the Compounds**: List the compounds provided in the question. For this example, let’s assume the compounds are: - Ethanol (C2H5OH) - Propan-2-one (acetone, C3H6O) - Pent-2-one (C5H10O) - Pent-3-one (C5H10O) 2. **Analyze Each Compound**: - **Ethanol (C2H5OH)**: This is a primary alcohol and can be oxidized to acetaldehyde (which has an alpha methyl group). Therefore, it gives a positive iodoform test. - **Propan-2-one (C3H6O)**: This is a methyl ketone (CH3COCH3) and has an alpha methyl group. It gives a positive iodoform test. - **Pent-2-one (C5H10O)**: This is also a methyl ketone (CH3C(=O)C4H9) with an alpha methyl group. It gives a positive iodoform test. - **Pent-3-one (C5H10O)**: This compound has the structure CH3C(=O)C2H5C2H5. It does not have an alpha methyl group adjacent to the carbonyl carbon, so it does not give a positive iodoform test. 3. **Conclusion**: The compound that does not give the iodoform test is **Pent-3-one**. ### Final Answer: **Pent-3-one does not give the iodoform test.**

To determine which of the following compounds does not give the iodoform test, we need to understand the conditions under which the iodoform test is positive. The iodoform test is typically given by: 1. **Methyl ketones** (compounds with the structure RCOCH3, where R can be any alkyl group). 2. **Ethanol** and other primary alcohols that can be oxidized to methyl ketones. 3. **Secondary alcohols** that can be oxidized to methyl ketones. The key factor for a compound to give a positive iodoform test is the presence of an **alpha methyl group** (a methyl group adjacent to the carbonyl carbon). ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |16 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |16 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |28 Videos
  • AMINES

    PHYSICS WALLAH|Exercise NEET Past 5 Years Questions |11 Videos

Similar Questions

Explore conceptually related problems

Which of the following compounds neither gives iodoform test nor responds to Tollen's test?

Which of the following compound does not give Tollen's test ?

Which of the following compounds will give iodoform test with I_(2)//NaOH

Which of the following does not given iodoform test :

Which of the following does not given iodoform test ?

Which of the following does not give iodoform test?

PHYSICS WALLAH-ALDEHYDES, KETONES AND CARBOXYLIC ACID -LEVEL - 2
  1. The only aldehyde which undergoes haloform reaction is

    Text Solution

    |

  2. A compound with molecular formula, C(4)H(8)O gives a positive haloform...

    Text Solution

    |

  3. Which of the following compound does not give iodoform test ?

    Text Solution

    |

  4. Which of the following reactions represent incorrect major product.

    Text Solution

    |

  5. Clemmensen reduction cannot be used to convert carbonyl group into CH(...

    Text Solution

    |

  6. Tollen's reagent is

    Text Solution

    |

  7. Oxidation of compound X gives a product which reacts with phenylhydraz...

    Text Solution

    |

  8. Fehiling's solution is

    Text Solution

    |

  9. A compound gives a yellow precipitate on warming with iodine and aq. S...

    Text Solution

    |

  10. The acid D obtained through the following sequence of reactions is: ...

    Text Solution

    |

  11. Which of the following will not undergo Hell-Volhard Zelinsky (HVZ) re...

    Text Solution

    |

  12. Which of the following is correct order of esterification of following...

    Text Solution

    |

  13. Diazomethane reacts with carboxylic acids to form

    Text Solution

    |

  14. The decreasing order of reactivity towards nucleophilic acyl substitut...

    Text Solution

    |

  15. Acetophenone can be prepared by Friedel crafts reaction between benzen...

    Text Solution

    |

  16. The general order of reactivity of carbonyl compounds for nucleophilic...

    Text Solution

    |

  17. The correct order of reactivity of PhMgBr with given compound is und...

    Text Solution

    |

  18. Which of the following does not give benzoic acid salt on oxidation wi...

    Text Solution

    |

  19. If formaldehyde and KOH are heated, then we get

    Text Solution

    |

  20. The final product in the following reaction is :

    Text Solution

    |