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The correct sequence of reaction to be p...

The correct sequence of reaction to be performed to convert benzene into m-bromoaniline is:

A

Nitration, reduction, bromination

B

Bromination, nitration, reduction

C

Nitration, bromination, reduction

D

Reduction, nitration, bromination

Text Solution

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The correct Answer is:
To convert benzene into m-bromoaniline, we need to follow a specific sequence of reactions. Here is a step-by-step solution: ### Step 1: Nitration of Benzene - **Reaction**: Treat benzene (C6H6) with a mixture of concentrated nitric acid (HNO3) and concentrated sulfuric acid (H2SO4). - **Product**: This will introduce a nitro group (-NO2) to the benzene ring, resulting in nitrobenzene (C6H5NO2). ### Step 2: Bromination of Nitrobenzene - **Reaction**: Next, we perform bromination on nitrobenzene using bromine (Br2) in the presence of a catalyst like iron (Fe) or aluminum chloride (AlCl3). - **Product**: The nitro group is a meta-directing group, so bromination will occur at the meta position relative to the nitro group. This will yield m-bromonitrobenzene (C6H4BrNO2). ### Step 3: Reduction of m-Bromonitrobenzene - **Reaction**: Finally, we reduce m-bromonitrobenzene using a reducing agent such as tin (Sn) in hydrochloric acid (HCl) or iron (Fe) in HCl. - **Product**: This reduction will convert the nitro group (-NO2) into an amino group (-NH2), resulting in m-bromoaniline (C6H4BrNH2). ### Summary of Steps 1. **Nitration**: Benzene + HNO3/H2SO4 → Nitrobenzene 2. **Bromination**: Nitrobenzene + Br2 → m-Bromonitrobenzene 3. **Reduction**: m-Bromonitrobenzene + Sn/HCl → m-Bromoaniline ### Final Product The final product of this sequence is m-bromoaniline. ---

To convert benzene into m-bromoaniline, we need to follow a specific sequence of reactions. Here is a step-by-step solution: ### Step 1: Nitration of Benzene - **Reaction**: Treat benzene (C6H6) with a mixture of concentrated nitric acid (HNO3) and concentrated sulfuric acid (H2SO4). - **Product**: This will introduce a nitro group (-NO2) to the benzene ring, resulting in nitrobenzene (C6H5NO2). ### Step 2: Bromination of Nitrobenzene - **Reaction**: Next, we perform bromination on nitrobenzene using bromine (Br2) in the presence of a catalyst like iron (Fe) or aluminum chloride (AlCl3). ...
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