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Which of the following reactions is appr...

Which of the following reactions is appropriate for converting acetamide to methamine?

A

Gabriels phthalimide synthesis

B

Carbylamine reaction

C

Hoffmann bromamide reaction

D

Stephens reaction

Text Solution

Verified by Experts

The correct Answer is:
C

Hoffmann bromamide reaction
`R-overset(O)overset(||)C-NH_2+Br_2+4NaOHrarrR-NH_2+Na_2CO_2+2NaBr+2H_2O`
Hoffmann developed a method for preparation of primary amines by treating an amide with brommine in an ethanoic solution of sodium hydroxide In this degradation reaction , migration of an alkyl or aryl group takes place from so formed contains one carbon less than that present in the amide.
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