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The correct statement regarding the basi...

The correct statement regarding the basicity of arylamines is .

A

Arylamines are generally more basic than alkylamines. because the nitrogen atom in arylamines is sphybridised.

B

Arylamines are generally less basic than alkylamines because the nitrogen lone pair electrons are delocalized by interaction with the aromatic ring `pi` electrons system.

C

Arylamines are generally more basic than alkylamines because the nitrogen lone pair electrons are not delocalised by interaction with the aromatic ring `pi` electron system.

D

Arylamines are generally more basic than alkylamines because of aryl group .

Text Solution

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The correct Answer is:
B

Arylamines are less basic than alkylamines as Non the benzene ring is in conjugation. Where its lone pair of electron are delocalised and partial-it-bond character is present thus making it unavailable for incoming electrophile, whereas in alkylamines such a process is not present and also -- effect increases the basic character on N.
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