Home
Class 12
CHEMISTRY
SF6 is known but SCl6 is not. Why?...

`SF_6` is known but `SCl_6` is not. Why?

Text Solution

Verified by Experts

Fluorine atom is smaller in size, so six `F^(-)` ions can surround a sulphur atom. The case is not so with chlorine atom due to its large size. So, `SF_6` is known but `SCI_6` is not known duc to interionic repulsion between larger `Cl^(-)` ions.
Promotional Banner

Topper's Solved these Questions

  • GROUP 16 ELEMENTS: OXYGEN FAMILY

    ARIHANT PUBLICATION|Exercise QUESTIONS FOR PRACTICE (LONG ANSWER TYPE QUESTIONS)|11 Videos
  • GROUP 16 ELEMENTS: OXYGEN FAMILY

    ARIHANT PUBLICATION|Exercise ODISHA BUREAU.S TEXTBOOK SOLUTIONS (A MULTIPLE CHOICE TYPE QUESTIONS)|30 Videos
  • GROUP 16 ELEMENTS: OXYGEN FAMILY

    ARIHANT PUBLICATION|Exercise QUESTIONS FOR PRACTICE (VERY SHORT ANSWER TYPE QUESTIONS)|26 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    ARIHANT PUBLICATION|Exercise CHAPTER PRACTICE (Long Answer Type Questions )|4 Videos
  • GROUP 17 ELEMENTS : HALOGEN FAMILY

    ARIHANT PUBLICATION|Exercise CHAPTER PRACTICE (Long Answer Type Questions)|1 Videos

Similar Questions

Explore conceptually related problems

PCl_5 is known but PI_5 is not known. Why ?

Why OF_6 does not exist but SF_6 exists ?

SF_6 is inert towards hydrolysis. Why?

MX_(5) (M =P, As, Sb and Bi) are known but MH_(5) are not known, why?

Chemical properties of astatine in comparison with other halogens is known very little to us. Why?

SF_6 exists while OF_6 does not. Explain.

Explain the following : Xe shows +8 oxidation state (e.g XeO_(4)) but XeF_(8) is not known why ?

Why is OF_6 not known?

ARIHANT PUBLICATION-GROUP 16 ELEMENTS: OXYGEN FAMILY-QUESTIONS FOR PRACTICE (SHORT ANSWER TYPE I QUESTIONS)
  1. Why is oxygen a gas sulphur a solid at while room temperature ?

    Text Solution

    |

  2. There is a large difference between the melting and boiling points of ...

    Text Solution

    |

  3. SF6 is known but SCl6 is not. Why?

    Text Solution

    |

  4. SF6 is inert towards hydrolysis. Why?

    Text Solution

    |

  5. Out of H2O and H2S, which one has higher bond angle and why?

    Text Solution

    |

  6. What is the action of ozone with lead sulphide? Give equation.

    Text Solution

    |

  7. How does Ozone react with KI solution ?

    Text Solution

    |

  8. What happens when O3 is passed through acidified SnCl2 solution ?

    Text Solution

    |

  9. Why is ozone not collected over mercury?

    Text Solution

    |

  10. Complete the equation given below and make it a balanced equation Sn...

    Text Solution

    |

  11. What happens when SO2gas is passed through lime water first slowly and...

    Text Solution

    |

  12. What happens when SO2 is passed through sulphuretted-hydrogen dissolve...

    Text Solution

    |

  13. Why hydrogen sulphide cannot be dried by conc. H2SO4?

    Text Solution

    |

  14. How do the following pairs of compounds react? H2S+SO2 rarr

    Text Solution

    |

  15. What happens when Sulphur dioxide is passed through FeCl3 solution ?

    Text Solution

    |

  16. Explain bleaching action of sulphur dioxide.

    Text Solution

    |

  17. How is the presence of SO2 detected?

    Text Solution

    |

  18. Comment on the nature of two S-O bonds formed in SO2 molecule. Are the...

    Text Solution

    |

  19. What happens when potassium bromide is treated with warm conc. sulphur...

    Text Solution

    |

  20. What happens when copper is heated with concentrated H2SO4? Give equat...

    Text Solution

    |