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Calculate relative rate of effusion of S...

Calculate relative rate of effusion of `SO_(2)" to "CH_(4)`, if the mixture obtained by effusing out a mixture with molar ratio `(n_(SO_2))/(n_(CH_4))=(8)/(1)` for three effusing steps.

A

`2 : 1`

B

`1 : 4`

C

`1 : 2`

D

`3 : 1`

Text Solution

Verified by Experts

The correct Answer is:
C

`(P_(3(SO_2)))/(P_(3(CH_4)))=(P_(SO_2))/(P_(CH_4))((M_(CH_4))/(M_(SO_2)))^(3/2)`
`(8)/(1) = (P_(SO_2))(P_(CH_4))(1)/(8), (n_1(SO_2))/(n_(1(CH_4)))=1 therefore=(n_1(SO_2))/(n_(1(CH_4)))=sqrt((16)/(64))= (1)/(2)`
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