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The decreasing order of enthalpies of re...

The decreasing order of enthalpies of reaction for producing carbocation is:

A

`DeltaH_(1)^(@)gtDeltaH_(2)^(@)gtDeltaH_(3)^(@)gtDeltaH_(4)^(@)`

B

`DeltaH_(4)^(@)gtDeltaH_(1)^(@)gtDeltaH_(2)^(@)gtDeltaH_(3)^(@)`

C

`DeltaH_(3)^(@)gtDeltaH_(2)^(@)gtDeltaH_(1)^(@)gtDeltaH_(4)^(@)`

D

`DeltaH_(2)^(@)gtDeltaH_(1)^(@)gtDeltaH_(4)^(@)gtDeltaH_(3)^(@)`

Text Solution

Verified by Experts

The correct Answer is:
B

`R-ClrarrR^(+)+Cl^(Theta)DeltaH_(0)`
Bond Energy of carbon halogen bond `prop(1)/("Stability of carbocation")`
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BRILLIANT PUBLICATION-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES - PART II (ISOMERISM AND REACTION MECHANISM) -LEVEL-II (ASSERTION-REASON TYPE)
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