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Which is the correct reaction coordinate...

Which is the correct reaction coordinate diagram for the following solvolysis reaction?
, , ,

A

B

C

D

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The correct Answer is:
B
Highly endothermic so has high `DeltaG` of activation.

`3^(@)` carbocation is stabilised by `H_(2)O`. This `S_(N)1` reaction has three transition states and two intermediates.
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BRILLIANT PUBLICATION-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES - PART II (ISOMERISM AND REACTION MECHANISM) -LEVEL-II (ASSERTION-REASON TYPE)
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