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Which will undergo fastest S(N)2 substit...

Which will undergo fastest `S_(N)2` substitution reaction when treated with NaOH?

A

`H_(5)C_(2)-undersetunderset(H)(|)oversetoverset(CH_(3))(|)(C)-Br`

B

`CH_(3)-undersetunderset(CH_(3))(|)oversetoverset(CH_(3))(|)(C)-Br`

C

`H-undersetunderset(C_(2)H_(5))(|)oversetoverset(CH_(3))(|)(C)-Br`

D

`H-undersetunderset(Br)(|)oversetoverset(H)(|)(C)-CH_(2)-CH_(2)-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

Primary alkyl halides undergo bimolecular nucleophilic substitution most readily.
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BRILLIANT PUBLICATION-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES - PART II (ISOMERISM AND REACTION MECHANISM) -LEVEL-II
  1. In an S(N)2 substitution reaction of the type R-Br+Cl^(-)overset("DMF"...

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  2. The product of which of the following reactions has the highest ease t...

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  3. Which will undergo fastest S(N)2 substitution reaction when treated wi...

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  4. Under identical conditions, S(N)1 reaction will occur most efficient w...

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  5. Consider the reaction, RCHO+NH(2)NH(2)rarrRCH=N-NH(2). What type of re...

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  6. An incorrect statement with respect to S(N)1 and S(N)2 mechanism for a...

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  7. In which of the following molecules, the resonance effect is not prese...

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  8. For 1-methoxy-1, 3-butadiene, which of the following resonating struct...

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  9. Which of the following statements regarding resonance is not correct?

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  10. Amongst the given species, the best leaving group in a nucleophilic su...

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  11. The mechanism of the reaction between tert-butyl alcohol and hydroxide...

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  12. In which of the following pairs A is more stable than B?

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  13. Which of the following carbocations will not rearrange?

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  14. Which one of the following substitutents at para-position is most effe...

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  15. The order of decreasing ease of abstraction of hydrogen atoms in the f...

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  16. Which of the following reactions involves a nucleophile? (I) CH(3)CO...

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  17. In the following carbocation, H//CH(3) that is most likely to migrate ...

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  18. The hyperconjugative stabilities of tert-butyl cation and 2-butene, re...

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  19. If the carbocation rearranges to gain stability, it will rearrange to

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  20. p-chlorophenol is a stronger acid than phenol because

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