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Under identical conditions, S(N)1 reacti...

Under identical conditions, `S_(N)1` reaction will occur most efficient with:

A

tert-butyl chloride

B

1-chlorobutane

C

2-methyl-1-chloropropane

D

2-chlorobutane

Text Solution

Verified by Experts

The correct Answer is:
A
`S_(N)1` reaction is most effective in `3^(@)` carbon because of higher stability of `3^(@)` carbocation.
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BRILLIANT PUBLICATION-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES - PART II (ISOMERISM AND REACTION MECHANISM) -LEVEL-II
  1. The product of which of the following reactions has the highest ease t...

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  2. Which will undergo fastest S(N)2 substitution reaction when treated wi...

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  3. Under identical conditions, S(N)1 reaction will occur most efficient w...

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  4. Consider the reaction, RCHO+NH(2)NH(2)rarrRCH=N-NH(2). What type of re...

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  5. An incorrect statement with respect to S(N)1 and S(N)2 mechanism for a...

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  6. In which of the following molecules, the resonance effect is not prese...

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  7. For 1-methoxy-1, 3-butadiene, which of the following resonating struct...

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  8. Which of the following statements regarding resonance is not correct?

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  9. Amongst the given species, the best leaving group in a nucleophilic su...

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  10. The mechanism of the reaction between tert-butyl alcohol and hydroxide...

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  11. In which of the following pairs A is more stable than B?

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  12. Which of the following carbocations will not rearrange?

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  13. Which one of the following substitutents at para-position is most effe...

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  14. The order of decreasing ease of abstraction of hydrogen atoms in the f...

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  15. Which of the following reactions involves a nucleophile? (I) CH(3)CO...

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  16. In the following carbocation, H//CH(3) that is most likely to migrate ...

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  17. The hyperconjugative stabilities of tert-butyl cation and 2-butene, re...

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  18. If the carbocation rearranges to gain stability, it will rearrange to

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  19. p-chlorophenol is a stronger acid than phenol because

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  20. The major product in the reaction is:

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