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500 mL of a hydrocarbon gas burtn in exc...

500 mL of a hydrocarbon gas burtn in excess of oxygen yielded 2500 mL of `CO_(2)` and 3.0 litre of water vapour (all volumes measured at the same temperature and pressure). The formula of the hydrocarbon is:

A

`C_(3)H_(6)`

B

`C_(2)H_(4)`

C

`C_(5)H_(12)`

D

`CH_(4)`

Text Solution

Verified by Experts

The correct Answer is:
C

`C_(x)H_(y)+[x+(y)/(4)]O_(2)rarrxCO_(2)+(y)/(2)H_(2)O(v)`
`{:(500,0,0),(0,500x,(y)/(2)xx500):}`
Now, 500x = 2500 `therefore x=5, 500(y)/(2)=3000 therefore y=12 therefore` Alkane is `C_(5)H_(12)`.
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