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Assertion : 2,3-dimethyl but-2-ene is mo...

Assertion : 2,3-dimethyl but-2-ene is more stable than but-2-ene.
Reason : 2,3-dimethyl but-2-ene possesses 12 `alpha`-hydrogen atoms whereas but-2-ene possesses only 6`alpha`-hydrogen atoms and therefore former shows more pronounced hyperconjugation.

A

If both Assertion and Reason are correct and Reason is the correct explanation of Assertion.

B

If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.

C

If Assertion is correct , but Reason is incorrect.

D

If both Assertion and Reason are incorrect .

Text Solution

Verified by Experts

The correct Answer is:
A

The phenomenon of displacement of electrons by conjugative mechanism involving. `sigma`-and `pi`-electron is called hyperconjugation. It is arised when alkyl groups having atleast one H atom on the `alpha`-carbon atom attached to an unsaturated carbon atom are able to release electrons due to delocalisation of `sigma` and `pi`-bond. It is more pronounced if `alpha`-H atom are more in number. Thus, stability of alkenes has been explained in terms of hyper conjugation
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