Home
Class 12
CHEMISTRY
(-)2- methylbutan- 1 - ol on heating wit...

`(-)2`- methylbutan- `1` - ol on heating with conc. HCl gives `(+)1`- chloro - `2` - methylbutane by `SN^(2)` mechanism. Which of the following statement are correct
i) reaction proceeds through retension of configuration at stereocentre
ii) reaction proceeds through inversion of configuration at stereocentre
iii) reaction proceeds directly through a transition state
iv) reaction proceeds through carbocation intermediate

A

i and iii

B

i and iv

C

ii and iii

D

i, iii and iv

Text Solution

Verified by Experts

Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    BRILLIANT PUBLICATION|Exercise Level-II|37 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    BRILLIANT PUBLICATION|Exercise LEVEL - II (ASSERTION - REASON) |5 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Linked Comprehension Type)|9 Videos

Similar Questions

Explore conceptually related problems

SN_2 mechanism proceeds through the intervention of

In the following reactions : the rate of reacton of (I) is faster than that of (II) . By which mechanism do both the reactions proceed ?

Assertion: S_N2 reaction proceeds with racemisation while SN_1 reaction proceeds with complete stereochemical inversion. Reason : S_N2 is two step reaction while S_N1 is one step reaction.

Statement 1 : Hofmann bromamide reaction takes place between an amide and Br_2 in basic medium. Statement 2: The reaction proceeds by the formation of (R-overset(* *)N: )

Assertion : Action of HNO_(2) on propan-1-amine gives mainly propan-2-ol. Reason : The reaction proceeds via carbocation intermediate and so rearranged products are possible.

Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-oI. Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation

BRILLIANT PUBLICATION-HALOALKANES AND HALOARENES-Level-II
  1. When concentration of alkyl halide is tripled and the concentration of...

    Text Solution

    |

  2. CH(3)-overset(CH(3))overset(|)(CH)-CH(2)-CH(3)overset(Cl(2),hv)(to)C(5...

    Text Solution

    |

  3. (-)2- methylbutan- 1 - ol on heating with conc. HCl gives (+)1- chloro...

    Text Solution

    |

  4. 1,3 dichloro propane reacts with zinc or Nal gives (major product)

    Text Solution

    |

  5. Which of the following is most reactive towards E(2) reaction

    Text Solution

    |

  6. Dehydrobromination of the following is in the order (I)

    Text Solution

    |

  7. Order of reactivity towards nucleophilic substitution reaction of the ...

    Text Solution

    |

  8. O- Chlorotoluence reacts with NaNH(2) in liq. NH(3) to give o-toludine...

    Text Solution

    |

  9. The halide which will not react with benzene in presence of anhydrous ...

    Text Solution

    |

  10. R-Cl can be

    Text Solution

    |

  11. Which of the following statements are correct about electrophilic subs...

    Text Solution

    |

  12. Which is incorrectly matched

    Text Solution

    |

  13. the given compound is

    Text Solution

    |

  14. Chloroform on boiling with conc. aqueous or alcoholic KOH, the product...

    Text Solution

    |

  15. At higher temperature, iodoform reaction is given by

    Text Solution

    |

  16. C Cl(4) is a well known fire extinguisher. However, after using it to ...

    Text Solution

    |

  17. Which of the following will give yellow precipitate with l(2)//NaOH

    Text Solution

    |

  18. Assertion : Dipole moment of CH(3)F is greater than CH(3)Cl Reason :...

    Text Solution

    |

  19. Assertion : Chlorination of CH(4) with Cl(2)//hv produces traces of CH...

    Text Solution

    |

  20. Assertion : Optically active alkyl halide undergo racemisation in S(N)...

    Text Solution

    |