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Oxymercuration-demercuration of methylen...

Oxymercuration-demercuration of methylene cyclohexane gives

A

Cyclohexyl methanol

B

1-methyl cyclohexanol

C

2-methyl cyclohexanol

D

Cyclohexanol

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Oxymercuration-demercuration of 3-methylcyclopentene produces this/these product(s)

Acid catalysed hydration of alkene gives alcohol. In this reaction addition of water takes place according to Markownikoff's rule. Since intermediate carbocation is formed in this reaction, rearrangement of carbocation takes place. In oxymercuration-demercuration reaction hydration of alkene takes place according to Markownikoff's rule. Oxymercuration demercuration is a better process than the catalytic hydration of alkene because in oxymercuration-demercuration, no rearrangement is possible. In hydroboration oxidation, hydration of alkene takes place as if it is according to anti-Markownikoff's addition. In hydroboration oxidation reaction rearrangement is not possible. Both in oxymercuration-demercuration and hydroboration oxidation intermediate carbocation are not formed. The product formed in the following reaction is

on oxy mercuration-demercuration produces the major product:

on oxymercuration-demercuation produces the major product:

The least energetic conformation of cyclohexane is:

BRILLIANT PUBLICATION-ALCOHOL PHENOL AND ETHERS -LEVEL-II
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  14. The major product, in the reaction b/n neopentyl alcohol and Lucas rea...

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  17. The alcohol, that will give an yellow ppt, on heating with iodine and ...

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  18. How many structural isomers of C(5)H(12)O will answer iodoform test?

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