Bouveault-Blanc reduction of ethyl aceta...

Bouveault-Blanc reduction of ethyl acetate will give

Propanol and methanol

Ethanol and methanol

Ethanol and propanol

Ethanol only

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Reduction involves:

Self condensation of 2 moles of ethyl acetate in presence of sodium ethoxide yields

Colloidal silver is obtained by reduction of silver nitrate with : acetic acid, molecular hydrogen, glucose, fructose

Ethyl acetate is formed by the reaction between ethanol and acetic acid and equilibrium is represented as: 'CH_3 COOH_( )+C_2 H_5 OH_(l) hArr CH_3 COOC_2 H_5_(l)+H_2 O_(l)' i) Write the concentration ratio (reaction quotient), 'Q_c', for this reaction (note: water is not in excess and is not a solvent in this reaction) ii) At '293 K', if one starts with '1.00' mol of acetic acid and '0.18 mol' of ethanol, there is '0.171' mol of ethyl acetate in the final equilibrium mixture. Calculate the equilibrium constant. iii) Starting with '0.5' mol of ethanol and '1.0' mol of acetic acid and maintaining it at 293 ' K, '0.214' mol of ethyl acetate is found after sometime. Has equilibrium been reached?

3.5 ml ethyl acetate was added to a flask containing 100 ml of 0.1 M HCI placed in a thermostat maintained at 30^(@) C 5 ml of the reaction mixture was withdrawn at different interval of time and after chilling titrated against standard NaOH the following data were obtained Time (minutes) 0 75 119 183 infty NaOH used (mL) 9.62 12.10 13.10 14.75 21.05 From the above data show that the hydrolysis of ethyl acetate is a first order reaction

The reduction potential of hydrogen electrode will be negative if :

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BRILLIANT PUBLICATION-ALCOHOL PHENOL AND ETHERS -LEVEL-II

Bouveault-Blanc reduction of ethyl acetate will give
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