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The anions (A) form hexagonal closest pa...

The anions (A) form hexagonal closest packing and atoms ( C) occupy only 2/3 of octahedral voids in it, then the general formula of the compound is

A

CA

B

`A_(2)`

C

`C_(2)A_(3)`

D

`C_(3)A_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

Hexagonal close packing contains 6 atoms per unit cell and hence the number of octahedral voids per unit cell is 6. Hence, number of A atoms per unit cell = 6
and number of atoms per unit cell = `6xx2/3=4`
The formula of ionic compound is given as simplest formula and hence formula is `C_(2)A_(3)`.
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