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The gamma-form of iron has fcc structure...

The `gamma`-form of iron has fcc structure (edge length 386 pm) and `beta`-form has bcc structure (edge length 290 pm). The ratio of density in `gamma`-form and `beta`-form is

A

0.8481

B

1.02

C

1.57

D

0.6344

Text Solution

Verified by Experts

The correct Answer is:
A

`Z_(eff)` for fcc = 4 and for bcc = 2/unit cell
`rho_(gamma)/rho_(beta)=rho_("fcc")/rho_("bcc")=(Z_("eff(fcc)"))/(Z_("eff(bcc)"))xx((a_("bcc"))/a_("fcc"))^(3)=4/2xx(290/386)^(3)=0.8481`
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