Home
Class 12
CHEMISTRY
Assertion: In electrolysis, the quantity...

Assertion: In electrolysis, the quantity of electricity needed for depositing 1 mole of silver is different from that required for 1 mole of copper.
Reason: The molecular weights of silver and copper are different.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect

D

If both (A) and (R) are incorrect.

Text Solution

Verified by Experts

The correct Answer is:
B

The amount of electricity required for oxidation orreduction depends on stoichiometry of the electrode reaction.Forsilver, `(Ag_(aq)^(+)+e^(-)rarrAg_(s))` one mole ofelectron is required. For copper, `(Cu_(aq)^(2+)+2e^(-)rarrCu_(s))` two moles of electrons are required.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    BRILLIANT PUBLICATION|Exercise Questions|17 Videos
  • ELECTROCHEMISTRY

    BRILLIANT PUBLICATION|Exercise Level -I|50 Videos
  • ELECTROCHEMISTRY

    BRILLIANT PUBLICATION|Exercise LEVEL-I|35 Videos
  • D & F BLOCK ELEMENTS

    BRILLIANT PUBLICATION|Exercise Level -II|38 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    BRILLIANT PUBLICATION|Exercise LEVEL - II (ASSERTION - REASON) |5 Videos

Similar Questions

Explore conceptually related problems

The amount of electricity required to deposit 1 mole of aluminium from a solution of A Cl_3 will be

1 mole of a compound contains 1 mole of C and 2 moles of O. The molecular weight of the compound is

Assertion : 1 Faraday of electricity deposits 1 g equivalent of Ag,Cu or Al. Reason : 1 mole of electrons are required to reduce 1 mole of Ag^(+) or 1/2 mole of Cu^(2+) or 1/3 mole of Al^(3+) ions.

The quantity of electricity needed to liberate one gram equivalent weight of an element is : 1 ampere, 96500 ampere, 96500 coulombs, 96500 Faradays

The same quantity of electricity is passed through solutions of silver nitrate and cupric sulphate connected in series. If the weight of silver deposited is 0.54 g, calculate the weight of copper deposited. (Equivalent mass of Ag = 108, equivalent mass of Cu = 31.75)

Assertion : One coulomb of electric charge deposits weight equal to the electrochemical equivalent of the substance. Reason : One Faraday deposits one mole of the substance.

Faraday's first law of electrolysis: Amount of a substance deposited or liberated on respective electrode is directly proportional to the quantity of electricity following through the circuit. W prop Q rArr W= ZQ W= Zit where Z= electrochemical equivalent of the substance. (i) In order to deposit or liberate 1 mole of substance, integeral no of Faradays are required. (ii) In order to deposit one gram equivalent of substance, 1 Faraday electricity is required. Current efficiency = ("Actual yield")/("Theoritical yield") xx 100% For the reaction, 2CH_(3)COO^(-) rarr C_(2)H_(6)(g) + 2CO_(2)(g) + 2e^(-) . If current of 20A is passed for 965sec, volume of liberated gases measured at NTP is found to be 3.36 lit, then calculate current efficiency of the reaction

Assertion: The molecular weight of acetic acid in benzene and water is different Reason: Water is polar and benezne is non polar.

BRILLIANT PUBLICATION-ELECTROCHEMISTRY-LEVEL-II
  1. Assertion : 1 Faraday of electricity deposits 1 g equivalent of Ag,Cu ...

    Text Solution

    |

  2. Assertion : Equivalent conductance increase with dilution for an elect...

    Text Solution

    |

  3. Assertion : At the end of electrolysis using Pt electrodes, an aqueous...

    Text Solution

    |

  4. Assertion :wedge(eq)^(@)(CH(3)COOH) cannot be determined experimentall...

    Text Solution

    |

  5. Assertion: Specific conductance decreases with dilution whereas equiva...

    Text Solution

    |

  6. Resistance of 0.1 MKCI solution in a conductivity cell is 300 ohm and ...

    Text Solution

    |

  7. Assertion : Sodium ions are discharged in preference to hydrogen ions ...

    Text Solution

    |

  8. Assertion: An electrochemical cell can be set up only if the redox rea...

    Text Solution

    |

  9. Assertion : If lambda(Na)A^(@) + lambda(CI^(-))^(@) are molar limiti...

    Text Solution

    |

  10. Assertion : One coulomb of electric charge deposits weight equal to th...

    Text Solution

    |

  11. Assertion : (Ni)|(Ni^(2+))(1.0M)|| Au^(3+)(l.0M)|Au for this cell emf ...

    Text Solution

    |

  12. Assertion : Emf andpotential difference are not same for cell. Reason:...

    Text Solution

    |

  13. Assertion : Kohlrausch's law helps to find the molar conductivity of a...

    Text Solution

    |

  14. Assertion :In mercury cell, the electrolyte is a paste of KOH and ZnO....

    Text Solution

    |

  15. Assertion : Molar conductivity increases with decrease in concentratio...

    Text Solution

    |

  16. Assertion :A standard hydrogen electrode is also called reversible ele...

    Text Solution

    |

  17. Assertion: In electrolysis, the quantity of electricity needed for dep...

    Text Solution

    |

  18. Assertion : If an aqueous solution of NaCl is electrolysed, the produc...

    Text Solution

    |

  19. Assertion: The ratio of specific conductivity to the observed conducta...

    Text Solution

    |

  20. Assertion: According to Kohlrausch's law, the molar conductance of a s...

    Text Solution

    |