Home
Class 12
CHEMISTRY
A drug becomes ineffective after 30% dec...

A drug becomes ineffective after 30% decomposition. The original concentration of a sample was 5 mg/mL , which becomes 4.2 mg/mL during 20 months. Assuming the decomposition of first order, calculate the expiry time of the drug in months.

A

79.4 months

B

36.2 months

C

59.4 months

D

41.0 months

Text Solution

Verified by Experts

The correct Answer is:
D

`k=(2.303)/(t )log_(10)(a)/(a-x)=(2.303)/(20)log_(10)(a)/(a-x)=(2.303)/(20)log_(10)(5)/(4.2)=0.000872 month^(-1)`
`0.00872 =(2.3030)/(t)log_(10)(100)/(70)`,t=40.9 = 41 month
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    BRILLIANT PUBLICATION|Exercise LEVEL I|55 Videos
  • CARBOXYLIC ACIDS

    BRILLIANT PUBLICATION|Exercise LEVEL-II (Assertion -Reason)|4 Videos
  • CO-ORDINATION COMPOUNDS AND ORGANOMETALLICS

    BRILLIANT PUBLICATION|Exercise Level-II (Assertion- Reason)|4 Videos

Similar Questions

Explore conceptually related problems

The decomposition of N_(2)O_(5) according to the equation, 2N_(2)O_(5) (g) rarr 4NO_(2) (g) + O_(2) (g) is a first order reaction, After 30 minutes from the start of the decomposition in a closed vessel, the total pressure developed is found to be 284.5 mm Hg and on completion, the total pressure is 584.5 mm Hg. Calculate the rate constant of the reaction.

In a solution of 100 mL 0.5 M acetic acid, one g of active charcoal is added, which adsorbs acetic acid. It is found that the concentration of acetic acid becomes 0.49 M if surface area of charcoal is 3.01 xx 10^(2) m^2 , calculate the area occupied by single acetic acid molecule on surface of charcoal.

The catalytic decomposition of H_(2)O_(2) was studied by titrating it at different intervals with KMnO_(4) solution.Calcualte the rate constant from the following data assuming the reaction to be of the first order time t(seconds): 0 600 1200 KMnO_(4) (mL) :22.8 13.8 8.2

From the following data show that the decomposition of hydrogen peroxide in aqueous solution is a first order reaction what is the value of the rate constant Time (t) in minutes 0 10 20 30 40 V(mL) 25.0 20.0 15.7 12.5 9.6 Where V is volume of kMnO_(4) solution required decompose a definite volume of hydrogen peroixde

The following data were obtained for the decompostion dintirogen pentoxide in C Cl_(4) at 325 k Time (minutes): 10 15 20 25 infty volume of O_(2) evolved (mL):6.30 8.95 11.40 13.50 34.75 show that this is a first order reaction

From the following data for the decomposition of ammonium nitrite in aqueous solution,prove that the reaction is first order Time (minutes ) 10 15 20 25 infty Volume N_(2) (mL) 6.25 9.00 11.40 13.65 35.05

BRILLIANT PUBLICATION-CHEMICAL KINETICS -LEVEL II
  1. Which of the following graphs is correct for the following reaction? ...

    Text Solution

    |

  2. A reaction takes place in three steps with individual rate constant an...

    Text Solution

    |

  3. A drug becomes ineffective after 30% decomposition. The original conce...

    Text Solution

    |

  4. On introducing a catalyst at 500 K, the rate of a first order reaction...

    Text Solution

    |

  5. For a reaction A + B rarr C + D,if the concentration of A is doubled w...

    Text Solution

    |

  6. The bromination of acetone that occurs in acid solution is represen...

    Text Solution

    |

  7. The decomposition of N(2)O(5) according to the equation, 2N(2)O(5) (g...

    Text Solution

    |

  8. At 500 K, the half life period of a gaseous reaction at an initial pre...

    Text Solution

    |

  9. At a certain temperature, the half change period for the catalytic dec...

    Text Solution

    |

  10. According to the collision model of kinetics, certain activtion energy...

    Text Solution

    |

  11. The radioactive element, Thallium-201, is used medicinally as a radiot...

    Text Solution

    |

  12. For a reaction A rarr Product half-life measured for two different ...

    Text Solution

    |

  13. The metabolism of an antibiotic, A,is a first-order rate process. The ...

    Text Solution

    |

  14. 80% of a first order reaction was completed in 70 min. How much it wil...

    Text Solution

    |

  15. A first order reaction: A rarr Products and a second order reaction: ...

    Text Solution

    |

  16. In a certain reaction, 10% of the reactant decomposes in one hour, 20%...

    Text Solution

    |

  17. The mechanism of the reaction, 2NO+O(2)rarr2NO(2) is NO+NO underset...

    Text Solution

    |

  18. Diazonium salt decompose as : C(6)H(5)N(2)CI^(-)rarrC(6)H(5)CI+N(2) At...

    Text Solution

    |

  19. At 27^(@) C it was observed in the hydrogenation of a reaction, the pr...

    Text Solution

    |

  20. In a catalytic reaction involving the formation of ammonia by haber ...

    Text Solution

    |