Home
Class 12
CHEMISTRY
Diazonium salt decompose as : C(6)H(5)N(...

Diazonium salt decompose as : `C_(6)H_(5)N_(2)CI^(-)rarrC_(6)H_(5)CI+N_(2)` At `0^(@) C` the evolution of `N_(2)` becomes two times faster when the initial concentration of the salt is doubled. Thus, it is

A

A first order reaction

B

A second order reaction

C

Independent of the intial concentration of reactant

D

A zero order reaction

Text Solution

Verified by Experts

The correct Answer is:
A

`r_(1)=k["salt"]^(n), r_(2)=2r_(1)=k[2 "salt"]^(n)`
`(2r_(1))/(r_(1))=(2)^(n),(2)^(1)=(2)^(n)n=1`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    BRILLIANT PUBLICATION|Exercise LEVEL I|55 Videos
  • CARBOXYLIC ACIDS

    BRILLIANT PUBLICATION|Exercise LEVEL-II (Assertion -Reason)|4 Videos
  • CO-ORDINATION COMPOUNDS AND ORGANOMETALLICS

    BRILLIANT PUBLICATION|Exercise Level-II (Assertion- Reason)|4 Videos

Similar Questions

Explore conceptually related problems

Diazonium salt decomposes as mathbf(C)_(6) (H)_(5) (~N)_(2)^+(Cl)- rarr (C)_(6) (H)_(5) (Cl)+(N)_(2^(*)) At 0^(circ) (C) the' evolution of (N)_(2) becoomes two times faster when the initial concentration of the salt is doubled. Therefore it is

What is the concentration of 1.5N solution of H_(2)O_(2) in terms of volume ?

The volume of water to be added to 100cm^(3) of 0.5N H_(2)SO_(4) to get decinormal concentration is

When C_(6)H_(5)COCOC_(6)H_(5) is reduced with LiAlH_(4) the product formed has ______ stereoisomers.

The reagents required to convert C_(6) H_(5) - C -= CH into C_(6) H_(5) CH_(2) CH_(2) OH are

Examine the reactions given below: i) CH_(4)+Cl_(2)rarrCH_(3)+HCl ii) nCH_(2)=CH_(2)rarr(CH_(2)-CH_(2))_(n) iii) C_(6)H_(14)rarrC_(2)H_(6)+C_(4)H_(6) iv) CH_(3)OH+CH_(3)COOHrarrCH_(3)COOCH_(3)+H_(2)O Identify the following types of reactions from the above equations. a) Esterification reaction b) Thermal cracking c) Polymerisation d) Substitution reaction

BRILLIANT PUBLICATION-CHEMICAL KINETICS -LEVEL II
  1. In a certain reaction, 10% of the reactant decomposes in one hour, 20%...

    Text Solution

    |

  2. The mechanism of the reaction, 2NO+O(2)rarr2NO(2) is NO+NO underset...

    Text Solution

    |

  3. Diazonium salt decompose as : C(6)H(5)N(2)CI^(-)rarrC(6)H(5)CI+N(2) At...

    Text Solution

    |

  4. At 27^(@) C it was observed in the hydrogenation of a reaction, the pr...

    Text Solution

    |

  5. In a catalytic reaction involving the formation of ammonia by haber ...

    Text Solution

    |

  6. When the concentration of a reactant in reaction A rarr B is increase...

    Text Solution

    |

  7. The hydrolysis of an ester was carried out with 0.1 M H(2)SO(4) and 0...

    Text Solution

    |

  8. A reaction of the type A(g) + B(g) rarr Product is taking place in a ...

    Text Solution

    |

  9. The reaction 2NO(2) rarr2NO+O(2) is second order respect to NO(2). I...

    Text Solution

    |

  10. A first order reaction is carried out starting with 10 mol l^(-1) ...

    Text Solution

    |

  11. The reaction A(g)+2B(g) rarrC(g)+D(g) is an elementary process In an...

    Text Solution

    |

  12. The decomposition of A into product has value of k as 4.5 x10^(3) (s)^...

    Text Solution

    |

  13. According to the Cr(2)O(7)^(2-)+5H^(+)+3HNO(2) →2Cr ^ (3+) +3NO (3)^(−...

    Text Solution

    |

  14. In a particular reaction the time required to complete half of the r...

    Text Solution

    |

  15. For the reaction A+B rarr C+D doubling the concentration of both th...

    Text Solution

    |

  16. For the reaction 2N(2)O(5)rarr4NO(2)+O(2) the rate equation can be ex...

    Text Solution

    |

  17. At a certain moment in the reaction 2N(2)O(5)rarr4NO(2)+O(2)N(2)O(5) ...

    Text Solution

    |

  18. The reaction Ararr X is a first order reaction which takes place in a ...

    Text Solution

    |

  19. The activation energy of a reaction is 24.0 kcal mol^(-1) at 27^(@)C...

    Text Solution

    |

  20. Assertion : The rate of reaction whether exothermic or endothermic, in...

    Text Solution

    |