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Assertion : [Fe(CN)6]^(3-) is weakly par...

Assertion : `[Fe(CN)_6]^(3-)` is weakly paramagnetic while `[Fe(CN)_6]^(4-)`is diamagnetic.
Reason : `[Fe(CN)_6]^(3-)` has +3 oxidation state while `[Fe(CN)_6]^(4-)` has `+2` oxidation state.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but(R) is incorrect.

D

If both (A) and (R) are.incorrect.

Text Solution

Verified by Experts

The correct Answer is:
B

`[Fe(CN)_6]^(3-)` possesses unpaired electron to show paramagnetic nature while `[Fe(CN)_6]^(4-)`possesses no unpaired electron and thus shows diamagnetic nature.
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