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Assertion : When NO reacts with FeSO4, a...

Assertion : When NO reacts with `FeSO_4`, a brown coloured complex is formed.
Reason : In the complex, the coordination number of Fe is +6.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but(R) is incorrect.

D

If both (A) and (R) are.incorrect.

Text Solution

Verified by Experts

The correct Answer is:
B

The colour of the complex formed, `[Fe(H_2O)_5NO]^(2+)` is due to charge transfer (transfer of odd`e^(-)` on N to Fe, changing NO to `NO^(+)` and `Fe^(2+)` to `Fe^(+)`).
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