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Among the following alcohols, which one ...

Among the following alcohols, which one is most acidic?

A

`CH_(3)CH_(2)CH_(2)OH`

B

`CH_(3)-OH`

C

`CH_(3)-CH_(2)-OH`

D

Text Solution

Verified by Experts

The correct Answer is:
B

This is because alcohols are weaker acids than water. While going from primary to secondary to tertiary, the acidity of alcohols decreases. This decrease in acidity is due to two factors that increase the activation energy for proton removal, Increase of electron density on the oxygen atom.of the more highly-substituted alcohol, and steric hindrance (because the alkyl groups, which inhibits solvation of the resulting alkoxide ion)
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BRILLIANT PUBLICATION-ALCOHOL, PHENOL & ETHER -LEVEL II (ASSERTION - REASON TYPE)
  1. Among the following alcohols, which one is most acidic?

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  2. Assertion : Carbon oxygen bond length of phenol is slightly less than ...

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  3. Assertion : In alcohols, the boiling point decreases with decrease in...

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  4. Assertion : Alcohols and water are weaker acids than phenols. Reas...

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  5. Assertion : Bromination of phenol takes place even in the absence of...

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  6. Assertion : The cleavage of C-O bond in ethers takes place under dra...

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  7. Assertion: Dipolemoment ofphenol is smaller than that of methanol. R...

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  8. Assertion: Neopentyl alcohol on treatment with HCl gives neopentyl chl...

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  9. Assertion: Phenoxide ion on treatment with an active alkyl h...

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  10. Assertion:Phenol forms 2,4,6-tribromophenol on treatment with Br2 in c...

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  11. Assertion: Alcohols have higher boiling points than ethers of comparab...

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  12. Assertion: Commercially carboxylic acids are reduced to alcohols by co...

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  13. Assertion: Ethers are not prepared by the dehydration of secondary and...

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  14. Assertion: CO2 is non polar, while ROR is polar in nature. Reason: ...

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  15. Assertion: t-Butyl methyl ether is not prepared by the reaction of t-b...

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  16. Assertion: Anisole undergoes electrophilic substitution at o-and p-pos...

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  17. Assertion: Acid catalysed dehydration of tert-butanol proceeds faster ...

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  18. Assertion: Reaction of alcohols with SOCl2 is catalysed by the presenc...

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  19. Assertion: Solubility of n-alcohl in water decreases with increase in ...

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  20. Assertion: The bond angle in alcohols is slightly less than the tetr...

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  21. Assertion: Addition reaction of water to but-1-ene in acidic medium yi...

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