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An organic compound X on treatment with ...

An organic compound X on treatment with `K_(2)Cr_(2)O_(7)` in anhydrous medium gives a compound Y which reacts with `I_(2)` and sodium carbonate to form triiodomethane. The compound X is

A

`CH_(3)OH`

B

`CH_(3)COCH_(3)`

C

`CH_(3)CHO`

D

`CH_(3)CHOHCH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

The reaction is:
`CH_(3) - underset(OH)underset(|)CH-CH_(3) overset(K_(2)CrO_(3)) to CH_(3) - underset(O)underset(||)C -CH_(3) overset(Na_(2)CO_(3)) to underset("Iodoform Yellow ppt")(CHI_(3) + CH_(3)COONa)`
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