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Acid-catalysed hydration'of alkenes exce...

Acid-catalysed hydration'of alkenes except ethene leads to the formation of

A

primary alcohol

B

secondary or tertiary alcohol

C

mixture of primary and secondary alcohols

D

mixture of secondary and tertiary alcohols

Text Solution

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The correct Answer is:
B

Hydration of ethene gives a 1° alcochol, ie, ethanol while all other alkenes give either 2° or 3° alcohols.
`underset("Ethene")(CH_(2)=CH_(2)) overset((i) "conc" H_(2)SO_(4))underset((ii)H_(2)O, "boil") to underset(1^(@)"alcohol")(CH_(3)-CH_(2)OH)`
`R - CH = CH_(2) overset((i)"conc" H_(2)SO_(4))underset((ii)H_(2)O, "boil") to underset(2^(@) "Alcohol")(R-CHOH -CH_(3))`
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BRILLIANT PUBLICATION-ALCOHOL, PHENOL & ETHER -LEVEL II (ASSERTION - REASON TYPE)
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  5. Assertion : Bromination of phenol takes place even in the absence of...

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  6. Assertion : The cleavage of C-O bond in ethers takes place under dra...

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  10. Assertion:Phenol forms 2,4,6-tribromophenol on treatment with Br2 in c...

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  11. Assertion: Alcohols have higher boiling points than ethers of comparab...

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  12. Assertion: Commercially carboxylic acids are reduced to alcohols by co...

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  13. Assertion: Ethers are not prepared by the dehydration of secondary and...

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  14. Assertion: CO2 is non polar, while ROR is polar in nature. Reason: ...

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  15. Assertion: t-Butyl methyl ether is not prepared by the reaction of t-b...

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  16. Assertion: Anisole undergoes electrophilic substitution at o-and p-pos...

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  17. Assertion: Acid catalysed dehydration of tert-butanol proceeds faster ...

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  19. Assertion: Solubility of n-alcohl in water decreases with increase in ...

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  20. Assertion: The bond angle in alcohols is slightly less than the tetr...

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  21. Assertion: Addition reaction of water to but-1-ene in acidic medium yi...

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