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Which of the following compound is notpo...

Which of the following compound is notpossible in the Dow's process?

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
D

Dow.s process is the industrial process to produce phenol in which chlorobenzene is heated under pressure with aqueous sodium hydroxide. However the ion can give side reaction in the process. It cohtains.nucleophilic character at both oxygen atom and the carbon atom at para position. The benzene produced by the elimination phase of the reaction can men undergo addition by attack at, either nucleophilic centre: reaction at oxygen producing diphenyl ether and reaction at carbon produces 4-hydroxybiphenyl
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BRILLIANT PUBLICATION-ALCOHOL, PHENOL & ETHER -LEVEL II (ASSERTION - REASON TYPE)
  1. Which of the following compound is notpossible in the Dow's process?

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  2. Assertion : Carbon oxygen bond length of phenol is slightly less than ...

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  3. Assertion : In alcohols, the boiling point decreases with decrease in...

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  4. Assertion : Alcohols and water are weaker acids than phenols. Reas...

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  5. Assertion : Bromination of phenol takes place even in the absence of...

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  6. Assertion : The cleavage of C-O bond in ethers takes place under dra...

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  7. Assertion: Dipolemoment ofphenol is smaller than that of methanol. R...

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  8. Assertion: Neopentyl alcohol on treatment with HCl gives neopentyl chl...

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  9. Assertion: Phenoxide ion on treatment with an active alkyl h...

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  10. Assertion:Phenol forms 2,4,6-tribromophenol on treatment with Br2 in c...

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  11. Assertion: Alcohols have higher boiling points than ethers of comparab...

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  12. Assertion: Commercially carboxylic acids are reduced to alcohols by co...

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  13. Assertion: Ethers are not prepared by the dehydration of secondary and...

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  14. Assertion: CO2 is non polar, while ROR is polar in nature. Reason: ...

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  15. Assertion: t-Butyl methyl ether is not prepared by the reaction of t-b...

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  16. Assertion: Anisole undergoes electrophilic substitution at o-and p-pos...

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  17. Assertion: Acid catalysed dehydration of tert-butanol proceeds faster ...

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  18. Assertion: Reaction of alcohols with SOCl2 is catalysed by the presenc...

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  19. Assertion: Solubility of n-alcohl in water decreases with increase in ...

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  20. Assertion: The bond angle in alcohols is slightly less than the tetr...

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  21. Assertion: Addition reaction of water to but-1-ene in acidic medium yi...

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