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Define oxygen dissociation curve. Can yo...

Define oxygen dissociation curve. Can you suggest any reason for its sigmoidal pattern?

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These questions consist of two statements each,printed as Assertion and Reason.While answering these questions you are required to choose any one of the following four responses. Assertion:Oxygen dissociation curve of haemoglobin is sigmoid. Reason:Oxygen dissociation curve moves toward left side with increase in CO_2 concentration in the air.