Home
Class 12
CHEMISTRY
The reduction potential of a half-cell c...

The reduction potential of a half-cell consisting of a Pt electrode immersed in `1.5 M Fe^(2+)` and ` 0.015 M Fe^(3+)` solutin at `25^@ C` is `(E_(Fe^(3+)//Fe^(2+))^@ = 0.770 V)` is .

A

`0.652V`

B

`0.88V`

C

`0.710V`

D

`0.850V`

Text Solution

Verified by Experts

The correct Answer is:
A

`Fe^(3+) rarr Fe^(2+)`
`E_(cell) = 0.770 V -(0.0591)/(1)log.(1.5)/(0.015)`
`= 0.770 -0.059 xx 2 = 0.652 V`
Promotional Banner

Similar Questions

Explore conceptually related problems

What are the fractions of Fe^(2+) and Fe^(3+) in Fe_(0.93) O respectively ?

The % of Fe^(+2) in Fe_(0.93)O_(1.00) is .

Calculate DeltaG^(@) for the reaction : Cu^(2+)(aq) +Fe(s) hArr Fe^(2+)(aq) +Cu(s) . Given that E_(Cu^(2+)//Cu)^(@) = 0.34 V , E_(Fe^(+2)//Fe)^(@) =- 0.44 V

Calculate the potential of an indicator electrode versus the standard hydrogen electrode, which originally contained 0.1M MnO_(4)^(-) and 0.8M H^(+) and which was treated with Fe^(2+) necessary to reduce 90% of the MnO_(4) to Mn^(2+) MnO_(4)^(-) +8H^(+) +5e rarr Mn^(2+) +H_(2)O, E^(@) = 1.51V

Stadard reduction electrode potentials of three metals A,B and C are respectively +0.5V, -3.0V and -1.2V . The reducing powers of these metals are:

Calculate the euilibrium constant for the reaction, 2Fe^(3+) + 3I^(-) hArr 2Fe^(2+) + I_(3)^(-) . The standard reduction potential in acidic conditions are 0.77 V and 0.54 V respectivelu for Fe^(3+)//Fe^(2+) and I_(3)^(-)//I^(-) couples.