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The addition of 3g of a substance to 100...

The addition of `3g` of a substance to `100g C CI_(4)(M = 154 g mol^(-1))` raises the boiling point of `C CI_(4)` by `0.60^(@)C` if `K_(b)(C CI_(4))` is `5K mol^(-1) kg`, calculate (a) the freezing point depression (b) the relative lowering of vapour pressure (c) the osmotic pressure at `298K` and (d) the molar mass of the substance. Given: `K_(f) (C CI_(4)) = 31.8 K kg mol^(-1)` and `rho` (solution) `= 1.64 g cm^(-3)`

Text Solution

Verified by Experts

The correct Answer is:
(a) `3.793^(@)C` (b) `0.018`, (c) `4.65 atm`, (d) `251.5`
(a) `(Delta T_(t))/(Delta T_(b)) = (k_(f))/(k_(b))=Delta T_(f)=(0.6xx31.8)/(5.03)=3.793^(@)C`
(b) Relative lowering of vapour pressure =
`(n)/(n+N)=((3)/(251.5))/((3)/(251.5)+(100)/(154))=0.018`
(c ) `pi = CRT`
`n = (3)/(251.5)=0.012`
`v = (103)/(1.64) = 62.8 mL`
`pi = (0.012)/(0.0628)xx0.0821xx298=4.65` atm
(d) `0.6 = (5.03xx3xx1000)/(M_(W)xx100) = gt M_(W) = 251.5`
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