Home
Class 12
CHEMISTRY
The specific conducitvity of a saturated...

The specific conducitvity of a saturated solution of `AgCI` is ` 3.40 xx 10^-6 "ohm"^(-1) cm^(-1) ` at ` 25^@C`. If ` lambda_(Ag+) = 62.3 "ohm"^(-1) cm^2 "mol"^(-1)` and `lambda_(CI-) = 67.7 "ohm"^(-1) cm^2 "mol"^(-1)`, the solubility of `AgCI` at `25^@C` is.

A

`2.6xx10^(-5) "mol" L^(-1)`

B

`3.731xx10^(-3) "mol" L^(-1)`

C

`3.731xx10^(-5) "mol" L^(-1)`

D

`2.6xx10^(-3)g L^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

`lambda_(AgCl)=)62.3+67.7)Omega^(-) "mol"^(-1)`
`=130 Omega^(-)"mol"^(-1)`
`s=(kxx1000)/(lambda_(AgCl))=(3.4xx10^(-6)xx1000)/(130)=2.6xx10^(-5) "mol" L^(-1)`
Promotional Banner

Similar Questions

Explore conceptually related problems

The specific conductivity of a saturated solution of AgCl is 3.40xx10^(-6) ohm^(-1) cm^(-1) at 25^(@)C . If lambda_(Ag^(+))=62.3 ohm^(-1) cm^(2) "mol"^(-1) and lambda_(Cl^(-))=67.7 ohm^(-1) cm^(2) "mol"^(-1) , the solibility of AgCl at 25^(@)C is:

The specific conductance of a 0.01 M solution of KCl is "0.0014 ohm"^(-1)" cm"^(-1) at 25^(@)C . Its equivalent conductance is ...............

The specific conductivity of a saturated AgCI solution if found to be 2.12 xx 10^(-6)S cm^(-1) and that for water is 6 xx 10^(-8)S cm^(-1) . The solubility of AgCI is: (lambda_(eq)^(prop) = 103 S "equiv"^(-1) cm^(2))

The specific conductance at 25^(@)C of a saturated solution of SrSO_(4) is 1.482 xx 10^(-4) ohm^(-1) cm^(-1) while that of water used is 1.5 xx 10^(-6) mho cm^(-1) . Determine at 25^(@)C the solubility in g per litre of SrSO_(4) in water. molar ionic conductance of Sr^(2+) and SO_(4)^(2-) ions at infinite are 54.46 and 79.8 ohm^(-1) cm^(2) "mole"^(-1) respectively. [Sr = 87.6 S = 32, O =16]

Calculate the solubiltit and solubility product of Co_(2) [Fe(CN)_(6)] is water at 25^(@)C from the following data: conductivity of a saturated solution of Co_(2)[Fe(CN)_(6)] is 2.06 xx 10^(-6) Omega^(-1) cm^(-1) and that of water used 4.1 xx 10^(-7) Omega^(-1) cm^(-1) . The ionic molar conductivites of Co^(2+) and Fe(CN)_(6)^(4-) are 86.0 Omega^(-1)cm^(-1) mol^(-1) and 44.0 Omega^(-1) cm^(-1) mol^(-1) .

The conductivity of a saturated solution of Ag_(3)PO_(4) is 9 xx 10^(-6) S m^(-1) and its equivalent conductivity is 1.50 xx 10^(-4) Sm^(2) "equivalent"^(-1) . Th K_(sp) of Ag_(3)PO_(4) is:-

We have taken a saturated solultion of AgBr, K_(SP) is 12 xx 10^(-4) . If 10^(-7) M of AgNO_(3) are added to 1 L of this solution, find conductivity (specific conductance) of this solution in term of 10^(-7) Sm^(-1) units. Given, lambda_((Ag^(+)))^(@) = 6 xx 10^(-3) Sm^(2) mol^(-1) , lambda_((Br^(-)))^(@) = 8 xx 10^(-3) Sm^(2) mol^(-1) , lambda_((NO_(3)^(-)))^@ = 8 xx 10^(-3) Sm^(2) mol^(-1) . Neglect the contribution of solvent.

Molar conductance of 1M solution of weak acid HA is 20 ohm^(-1) cm^(2) mol^(-1) . Find % dissocation of HA : ((^^_(m)^(o)(H^(+)) =350 S cm^(2) mol^(-1)),(^^_(m)^(o)(A^(-)) =50 S cm^(2) mol^(-1)))