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The van der waal's gas equation is (P+a/...

The van der waal's gas equation is `(P+a/V^(2))(V-b)=RT`, where P is pressure, V is molar volume and T is the temperature of the given sample of gas. R is called molar gas constant, a and b are called van der waal's constants.
Which of the following does not posses the same dimensional formula as that for RT

A

PV

B

Pb

C

`a/V^(2)`

D

`(ab)/V^(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[PV]=[RT], [Pb]=[PV]=[RT]`
`[a/V^(2)]=[(PV^(2))/V^(2)]=[P] ne [RT]` and
`[(ab)/V^(2)]=[((PV^(2))V)/V^(2)]=[PV]=[RT]`
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