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The equilibrium constant (K) for the rea...

The equilibrium constant (K) for the reaction
`Fe^(2+)+(aq)Ag^(+)(aq)toFe^(3+)(aq)+Ag(s)` will be
Given `E^(@)(Fe^(3+)//Fe^(2+))=0.77V,`
`E^(@)(Ag^(+)//Ag)=0.80V`

A

100

B

3.16

C

10

D

0.5

Text Solution

Verified by Experts

The correct Answer is:
B
`E^(@)=(E_(RQ)^(@))_(Cat)-(E_(RP)^(@))_(Anode)`
`=0.80-0.77=0.03`
`n=1`
`DeltaG^(@)=--2.303xxRTlogK`
log K = 0.5
K=3.16
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