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In the following reaction order , B is ...

In the following reaction order , B is
`CH_(3)CH_(2)COOH overset (P//Br_(2)) to A overset (alc KOH) underset (H^(+)) to B`

A

`CH_(2)=CH-COOH`

B

`CH_(2)-underset(Br)underset(|)CH-COOH`

C

`CH_(3)CH_(2)COBr`

D

`CH_(3)CH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product B in the given reaction sequence, we will analyze each step carefully. ### Step 1: Identify the starting compound The starting compound is propionic acid, which has the formula: \[ \text{CH}_3\text{CH}_2\text{COOH} \] ### Step 2: Reaction with Bromine and Red Phosphorus When propionic acid is treated with bromine in the presence of red phosphorus, a bromination reaction occurs at the alpha carbon (the carbon adjacent to the carboxylic acid group). This reaction is known as the Hell-Volhard-Zelinsky reaction. In this case, one of the alpha hydrogens (attached to the alpha carbon) is replaced by a bromine atom. The product formed is: \[ \text{CH}_3\text{CHBr}\text{COOH} \] This compound is called 2-bromopropionic acid. ### Step 3: Reaction with Alcoholic KOH and H+ Next, the 2-bromopropionic acid undergoes elimination when treated with alcoholic KOH and an acid (H+). This elimination reaction involves the removal of HBr from the molecule. The elimination of HBr leads to the formation of a double bond between the alpha and beta carbons. The resulting product is: \[ \text{CH}_2=\text{CH}\text{COOH} \] This compound is known as acrylic acid or prop-2-enoic acid. ### Conclusion Thus, the final product B is: \[ \text{CH}_2=\text{CH}\text{COOH} \] ### Answer The correct answer is: \[ \text{B} = \text{CH}_2=\text{CH}\text{COOH} \]

To determine the product B in the given reaction sequence, we will analyze each step carefully. ### Step 1: Identify the starting compound The starting compound is propionic acid, which has the formula: \[ \text{CH}_3\text{CH}_2\text{COOH} \] ### Step 2: Reaction with Bromine and Red Phosphorus When propionic acid is treated with bromine in the presence of red phosphorus, a bromination reaction occurs at the alpha carbon (the carbon adjacent to the carboxylic acid group). This reaction is known as the Hell-Volhard-Zelinsky reaction. ...
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